ISI Web of Knowledge Alert - Sokhan VP

ISI Web of Knowledge Citation Alert

Cited Article: Sokhan VP. Fluid flow in nanopores: Accurate boundary conditions for carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Dual diffusion mechanism of argon confined in single-walled carbon nanotube bundles

Authors:
Liu, YC; Moore, JD; Roussel, TJ; Gubbins, KE

Author Full Names:
Liu, Ying-Chun; Moore, Joshua D.; Roussel, Thomas J.; Gubbins, Keith E.

Source:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS 12 (25): 6632-6640 2010

Language:
English

Document Type:
Article

KeyWords Plus:
MOLECULAR-DYNAMICS SIMULATIONS; TRANSPORT DIFFUSION; FILE DIFFUSION; SILICA; DIFFUSIVITIES; ADSORPTION; CATALYSIS; ALPO4-5; DEVICES; STORAGE

Abstract:
The adsorption and diffusion mechanisms of argon at 120 K were examined in a (25,0) single-walled carbon nanotube (SWCNT) bundle using a combination of Grand Canonical Monte Carlo and microcanonical molecular dynamics simulations. Interstices between the SWCNTs provided the most energetically favorable adsorption sites and filled completely at low relative pressure, followed by adsorption in the SWCNTs. We calculated the self-diffusivities from the average mean squared displacements of argon molecules. In both flexible and rigid bundles, we observed a bimodal diffusion mechanism, with single-file diffusion occurring in the interstitial sites and Fickian diffusion in the SWCNTs. Strong system size effects were observed in our simulations. The largest system sizes showed very little influence of the nanotube flexibility on the diffusion of argon even at the lowest pressures studied.

Reprint Address:
Gubbins, KE, N Carolina State Univ, Inst Computat Sci & Engn, Raleigh, NC 27695 USA.

Research Institution addresses:
[Liu, Ying-Chun; Moore, Joshua D.; Roussel, Thomas J.; Gubbins, Keith E.] N Carolina State Univ, Inst Computat Sci & Engn, Raleigh, NC 27695 USA; [Liu, Ying-Chun; Moore, Joshua D.; Roussel, Thomas J.; Gubbins, Keith E.] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA; [Liu, Ying-Chun] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

E-mail Address:
keg@ncsu.edu

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BHATIA SK, 2005, MOL SIMULAT, V31, P643, DOI 10.1080/00268970500108403.
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Cited Reference Count:
57

Times Cited:
0

Publisher:
ROYAL SOC CHEMISTRY; THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

Subject Category:
Chemistry, Physical; Physics, Atomic, Molecular & Chemical

ISSN:
1463-9076

DOI:
10.1039/b927152j

IDS Number:
611NW

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ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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PT J
*Record 1 of 1.
L5 <http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS&DestLinkType=FullRecord;UT=000278905700026>
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AU Yu, MA
Funke, HH
Falconer, JL
Noble, RD
AF Yu, Miao
Funke, Hans H.
Falconer, John L.
Noble, Richard D.
TI Gated Ion Transport through Dense Carbon Nanotube Membranes
SO JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
LA English
DT Article
ID WATER-ADSORPTION; CHANNEL; SELECTIVITY; CONDUCTION
AB Gated ion diffusion is found widely in hydrophobic biological
nanopores, upon changes in ligand binding, temperature, transmembrane
voltage, and mechanical stress. Because water is the main media for ion
diffusion in these hydrophobic biological pores, ion diffusion behavior
through these nanochannels is expected to be influenced significantly
when water wettability in hydrophobic biological nanopores is sensitive
and changes upon small external changes. Here, we report for the first
time that ion diffusion through highly hydrophobic nanopores (similar
to 3 nm) showed a gated behavior due to change of water wettability on
hydrophobic surface upon small temperature change or ultrasound. Dense
carbon nanotube (CNT) membranes with both 3-nm CNTs and 3-nm
interstitial pores were prepared by a solvent evaporation process and
used as a model system to investigate ion diffusion behavior. Ion
diffusion through these membranes exhibited a gated behavior. The ion
flux was turned on and off, apparently because the water wettability of
CNTs changed. At 298 K, ion diffusion through dense CNT membranes
stopped after a few hours, but it dramatically increased when the
temperature was increased 20 K or the membrane was subjected to
ultrasound. Likewise, water adsorption on dense CNT membranes increased
dramatically at a water activity of 0.53 when the temperature increased
from 293 to 306 K, indicating capillary condensation. Water adsorption
isotherms of dense CNT membranes suggest that the adsorbed water forms
a discontinuous phase at 293 K, but it probably forms a continuous
layer, probably in the interstitial CNT regions, at higher
temperatures. When the ion diffusion channel was opened by a
temperature increase or ultrasound, ions diffused through the CNT
membranes at a rate similar to bulk diffusion in water. This finding
may have implications for using CNT membrane for desalination and water
treatment.
C1 [Yu, Miao; Funke, Hans H.; Falconer, John L.; Noble, Richard D.] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA.
RP Falconer, JL, Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309
USA.
EM john.falconer@colorado.edu
CR BASS RB, 2002, SCIENCE, V298, P1582
CHANG G, 1998, SCIENCE, V282, P2220
CI LJ, 2007, ADV MAT, V19
CUSSLER EL, 1984, DIFFUSION MASS TRANS
DOYLE DA, 1998, SCIENCE, V280, P69
FORNASIERO F, 2008, P NATL ACAD SCI USA, V105, P17250, DOI
10.1073/pnas.0710437105
FUTABA DN, 2006, NAT MATER, V5, P987, DOI 10.1038/nmat1782
HARPST JA, 1965, J PHYS CHEM-US, V69, P2333
HATA K, 2004, SCIENCE, V306, P1362
HINDS BJ, 2004, SCIENCE, V303, P62, DOI 10.1126/science.1092048
HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298
HUMMER G, 2001, NATURE, V414, P188
KIM S, 2007, NANO LETT, V7, P2806, DOI 10.1021/nl071414u
LI JY, 2007, P NATL ACAD SCI USA, V104, P3687, DOI
10.1073/pnas.0604541104
MAJUMDER M, 2005, NATURE, V438, P44, DOI 10.1038/43844a
MAO SH, 2006, CHEM PHYS LETT, V421, P513, DOI
10.1016/j.cplett.2006.02.011
MURATA K, 2000, NATURE, V407, P599
NISHIZAWA M, 1995, SCIENCE, V268, P700
STRIOLO A, 2005, J CHEM PHYS, V122, ARTN 234712
VOETS T, 2004, NATURE, V430, P748, DOI 10.1038/nature02732
WANG HJ, 2008, SCIENCE, V322, P80, DOI 10.1126/science.1162412
YU M, 2009, NANO LETT, V9, P225, DOI 10.1021/nl802816h
NR 22
TC 0
PU AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
SN 0002-7863
DI 10.1021/ja9091769
PD JUN 23
VL 132
IS 24
BP 8285
EP 8290
SC Chemistry, Multidisciplinary
GA 612NJ
UT ISI:000278905700026
ER

EF

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ISI Web of Knowledge Alert - Majumder M

ISI Web of Knowledge Citation Alert

Cited Article: Majumder M. Nanoscale hydrodynamics - Enhanced flow in carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Analysis of pressure-driven electrokinetic flows in hydrophobic microchannels with slip-dependent zeta potential

Authors:
Soong, CY; Hwang, PW; Wang, JC

Author Full Names:
Soong, C. Y.; Hwang, P. W.; Wang, J. C.

Source:
MICROFLUIDICS AND NANOFLUIDICS 9 (2-3): 211-223 AUG 2010

Language:
English

Document Type:
Article

Author Keywords:
Microchannel flow; Electrokinetics; Hydrophobic channel; Slip effect; Apparent zeta potential

KeyWords Plus:
LIQUID FLOW; ELECTROOSMOTIC FLOW; MICROFLUIDICS

Abstract:
The present study is an analysis of pressure-driven electrokinetic flows in hydrophobic microchannels with emphasis on the slip effects under coupling of interfacial electric and fluid slippage phenomena. Commonly used linear model with slip-independent zeta potential and the nonlinear model at limiting (high-K) condition with slip-dependent zeta potential are solved analytically. Then, numerical solutions of the electrokinetic flow model with zeta potential varying with slip length are analyzed. Different from the general notion of "the more hydrophobic the channel wall, the higher the flowrate," the results with slip-independent and slip-dependent zeta potentials both disclose that flowrate becomes insensitive to the wall hydrophobicity or fluid slippage at sufficiently large slip lengths. Boundary slip not only assists fluid motion but also enhances counter-ions transport in EDL and, thus, results in strong streaming potential as well as electrokinetic retardation. With s!
lip-dependent zeta potential considered, flowrate varies non-monotonically with increasing slip length due to competition of the favorable and adverse effects with more complicated interactions. The influence of the slip on the electrokinetic flow is eventually nullified at large slip lengths for balance of the counter effects, and the flowrate becomes insensitive to further hydrophobicity of the microchannel. The occurrence of maximum, minimum, and insensitivity on the flowrate-slip curves can be premature at a higher zeta potential and/or larger electrokinetic separation distance.

Reprint Address:
Soong, CY, Feng Chia Univ, Dept Aerosp & Syst Engn, Taichung 40724, Taiwan.

Research Institution addresses:
[Soong, C. Y.; Hwang, P. W.; Wang, J. C.] Feng Chia Univ, Dept Aerosp & Syst Engn, Taichung 40724, Taiwan

E-mail Address:
cysoong@fcu.edu.tw

Cited References:
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FERZIGER JH, 1999, COMPUTATIONAL METHOD.
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MAJUMDER M, 2005, NATURE, V438, P44, DOI 10.1038/43844a.
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TANDON V, 2008, ELECTROPHORESIS, V29, P1102, DOI 10.1002/elps.200800735.
TRETHEWAY DC, 2002, PHYS FLUIDS, V14, P9.
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VENDITTI R, 2006, MICROFLUID NANOFLUID, V2, P493, DOI 10.1007/s10404-006-0100-0.
VERONOV RS, 2008, IND ENG CHEM REV, V47, P2455.
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YANG J, 2003, J COLLOID INTERF SCI, V260, P225, DOI 10.1016/S0021-9797(02)00158-3.
YANG J, 2003, J MICROMECH MICROENG, V13, P113.
YANG J, 2004, ANAL CHIM ACTA, V507, P39, DOI 10.1016/j.aca.2003.12.043.
ZHU YX, 2001, PHYS REV LETT, V87, ARTN 096105.
ZIMMERMANN R, 2006, MICROFLUID NANOFLUID, V2, P367, DOI 10.1007/s10404-006-0087-6.

Cited Reference Count:
25

Times Cited:
0

Publisher:
SPRINGER HEIDELBERG; TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY

Subject Category:
Nanoscience & Nanotechnology; Instruments & Instrumentation; Physics, Fluids & Plasmas

ISSN:
1613-4982

DOI:
10.1007/s10404-009-0536-0

IDS Number:
612VJ

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Title:
Gated Ion Transport through Dense Carbon Nanotube Membranes

Authors:
Yu, MA; Funke, HH; Falconer, JL; Noble, RD

Author Full Names:
Yu, Miao; Funke, Hans H.; Falconer, John L.; Noble, Richard D.

Source:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132 (24): 8285-8290 JUN 23 2010

Language:
English

Document Type:
Article

KeyWords Plus:
WATER-ADSORPTION; CHANNEL; SELECTIVITY; CONDUCTION

Abstract:
Gated ion diffusion is found widely in hydrophobic biological nanopores, upon changes in ligand binding, temperature, transmembrane voltage, and mechanical stress. Because water is the main media for ion diffusion in these hydrophobic biological pores, ion diffusion behavior through these nanochannels is expected to be influenced significantly when water wettability in hydrophobic biological nanopores is sensitive and changes upon small external changes. Here, we report for the first time that ion diffusion through highly hydrophobic nanopores (similar to 3 nm) showed a gated behavior due to change of water wettability on hydrophobic surface upon small temperature change or ultrasound. Dense carbon nanotube (CNT) membranes with both 3-nm CNTs and 3-nm interstitial pores were prepared by a solvent evaporation process and used as a model system to investigate ion diffusion behavior. Ion diffusion through these membranes exhibited a gated behavior. The ion flux was turned on an!
d off, apparently because the water wettability of CNTs changed. At 298 K, ion diffusion through dense CNT membranes stopped after a few hours, but it dramatically increased when the temperature was increased 20 K or the membrane was subjected to ultrasound. Likewise, water adsorption on dense CNT membranes increased dramatically at a water activity of 0.53 when the temperature increased from 293 to 306 K, indicating capillary condensation. Water adsorption isotherms of dense CNT membranes suggest that the adsorbed water forms a discontinuous phase at 293 K, but it probably forms a continuous layer, probably in the interstitial CNT regions, at higher temperatures. When the ion diffusion channel was opened by a temperature increase or ultrasound, ions diffused through the CNT membranes at a rate similar to bulk diffusion in water. This finding may have implications for using CNT membrane for desalination and water treatment.

Reprint Address:
Falconer, JL, Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA.

Research Institution addresses:
[Yu, Miao; Funke, Hans H.; Falconer, John L.; Noble, Richard D.] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA

E-mail Address:
john.falconer@colorado.edu

Cited References:
BASS RB, 2002, SCIENCE, V298, P1582.
CHANG G, 1998, SCIENCE, V282, P2220.
CI LJ, 2007, ADV MAT, V19.
CUSSLER EL, 1984, DIFFUSION MASS TRANS.
DOYLE DA, 1998, SCIENCE, V280, P69.
FORNASIERO F, 2008, P NATL ACAD SCI USA, V105, P17250, DOI 10.1073/pnas.0710437105.
FUTABA DN, 2006, NAT MATER, V5, P987, DOI 10.1038/nmat1782.
HARPST JA, 1965, J PHYS CHEM-US, V69, P2333.
HATA K, 2004, SCIENCE, V306, P1362.
HINDS BJ, 2004, SCIENCE, V303, P62, DOI 10.1126/science.1092048.
HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298.
HUMMER G, 2001, NATURE, V414, P188.
KIM S, 2007, NANO LETT, V7, P2806, DOI 10.1021/nl071414u.
LI JY, 2007, P NATL ACAD SCI USA, V104, P3687, DOI 10.1073/pnas.0604541104.
MAJUMDER M, 2005, NATURE, V438, P44, DOI 10.1038/43844a.
MAO SH, 2006, CHEM PHYS LETT, V421, P513, DOI 10.1016/j.cplett.2006.02.011.
MURATA K, 2000, NATURE, V407, P599.
NISHIZAWA M, 1995, SCIENCE, V268, P700.
STRIOLO A, 2005, J CHEM PHYS, V122, ARTN 234712.
VOETS T, 2004, NATURE, V430, P748, DOI 10.1038/nature02732.
WANG HJ, 2008, SCIENCE, V322, P80, DOI 10.1126/science.1162412.
YU M, 2009, NANO LETT, V9, P225, DOI 10.1021/nl802816h.

Cited Reference Count:
22

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Multidisciplinary

ISSN:
0002-7863

DOI:
10.1021/ja9091769

IDS Number:
612NJ

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ISI Web of Knowledge Alert - Thompson, P

ISI Web of Knowledge Citation Alert

Cited Article: Thompson, P. A general boundary condition for liquid flow at solid surfaces
Alert Expires: 09 NOV 2010
Number of Citing Articles: 3 new records this week (3 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Corrected second-order slip boundary condition for fluid flows in nanochannels

Authors:
Zhang, HW; Zhang, ZQ; Zheng, YG; Ye, HF

Author Full Names:
Zhang, Hongwu; Zhang, Zhongqiang; Zheng, Yonggang; Ye, Hongfei

Source:
PHYSICAL REVIEW E 81 (6): Art. No. 066303 Part 2 JUN 8 2010

Language:
English

Document Type:
Article

KeyWords Plus:
MOLECULAR-DYNAMICS SIMULATION; INHOMOGENEOUS FLUIDS; CONFINED LIQUIDS; SOLID INTERFACE; GAS; SOLIDIFICATION; SURFACES

Abstract:
A corrected second-order slip boundary condition is proposed to solve the Navier-Stokes equations for fluid flows confined in parallel-plate nanochannels. Compared with the classical second-order slip boundary condition proposed by Beskok and Karniadakis, the corrected slip boundary condition is not only dependent on the Knudsen number and the tangential momentum accommodation coefficient, but also dependent on the relative position of the slip surface in the Knudsen layer. For the fluid flows in slip-flow regime with the Knudsen number less than 0.3, Couette cell is investigated using molecular-dynamics simulations to verify Newtonian flow behaviors by examining the constitutive relationship between shear stress and strain rate. By comparing the velocity profiles of Poiseuille flows predicted from the Navier-Stokes equations with the corrected slip boundary condition with that from molecular-dynamics simulations, it is found that the flow behaviors in our models can be effe!
ctively captured.

Reprint Address:
Zhang, HW, Dalian Univ Technol, Fac Vehicle Engn & Mech, Dept Engn Mech, State Key Lab Struct Anal Ind Equipment, Dalian 116024, Peoples R China.

Research Institution addresses:
[Zhang, Hongwu; Zhang, Zhongqiang; Zheng, Yonggang; Ye, Hongfei] Dalian Univ Technol, Fac Vehicle Engn & Mech, Dept Engn Mech, State Key Lab Struct Anal Ind Equipment, Dalian 116024, Peoples R China

E-mail Address:
zhanghw@dlut.edu.cn

Cited References:
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LI J, 1998, PHYS REV E, V57, P7259.
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Cited Reference Count:
36

Times Cited:
0

Publisher:
AMER PHYSICAL SOC; ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA

Subject Category:
Physics, Fluids & Plasmas; Physics, Mathematical

ISSN:
1539-3755

DOI:
10.1103/PhysRevE.81.066303

IDS Number:
607II

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Title:
Viscous heating in nanoscale shear driven liquid flows

Authors:
Kim, BH; Beskok, A; Cagin, T

Author Full Names:
Kim, Bo Hung; Beskok, Ali; Cagin, Tahir

Source:
MICROFLUIDICS AND NANOFLUIDICS 9 (1): 31-40 JUL 2010

Language:
English

Document Type:
Article

Author Keywords:
Nano-scale heat transfer; Kapitza resistance; Kapitza length; Shear flow; Viscous heating

KeyWords Plus:
MOLECULAR-DYNAMICS SIMULATION; BOUNDARY-CONDITIONS; THERMAL TRANSPORT; SOLID INTERFACE; FOURIER-LAW; FLUID-FLOW; EQUILIBRIUM; MECHANICS; SURFACES; STATES

Abstract:
Three-dimensional Molecular Dynamics (MD) simulations of heat and momentum transport in liquid Argon filled shear-driven nano-channels are performed using 6-12 Lennard-Jones potential interactions. Work done by the viscous stresses heats the fluid, which is dissipated through the channel walls, maintained at isothermal conditions through a recently developed interactive thermal wall model. Shear driven nano-flows for weak wetting surfaces (epsilon (wf) /epsilon a parts per thousand currency sign 0.6) are investigated. Spatial variations in the fluid density, kinematic viscosity, shear- and energy dissipation rates are presented. Temperature profiles in the nano-channel are obtained as a function of the surface wettability, shear rate and the intermolecular stiffness of wall molecules. The energy dissipation rate is almost a constant for epsilon (wf) /epsilon a parts per thousand currency sign 0.6, which results in parabolic temperature profiles in the domain with temperature!
jumps due to the well known Kapitza resistance at the liquid/solid interfaces. Using the energy dissipation rates predicted by MD simulations and the continuum energy equation subjected to the temperature jump boundary conditions developed in [Kim et al. Journal of Chemical Physics, 129, 174701, 2008b], we obtain analytical solutions for the temperature profiles, which agree well with the MD results.

Reprint Address:
Beskok, A, Old Dominion Univ, Dept Aerosp Engn, Norfolk, VA 23529 USA.

Research Institution addresses:
[Kim, Bo Hung; Beskok, Ali] Old Dominion Univ, Dept Aerosp Engn, Norfolk, VA 23529 USA; [Cagin, Tahir] Texas A&M Univ, Dept Chem Engn, College Stn, TX 77840 USA

E-mail Address:
abeskok@odu.edu

Cited References:
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Cited Reference Count:
31

Times Cited:
0

Publisher:
SPRINGER HEIDELBERG; TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY

Subject Category:
Nanoscience & Nanotechnology; Instruments & Instrumentation; Physics, Fluids & Plasmas

ISSN:
1613-4982

DOI:
10.1007/s10404-009-0515-5

IDS Number:
607SH

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Title:
Direct transition of potential of water droplets to electric energy using aligned single-walled carbon nanotubes

Authors:
Liu, J; Zheng, KH; Liu, Z; Hu, LJ; Sun, LF

Author Full Names:
Liu Ji; Zheng Kai-Hong; Liu Zheng; Hu Li-Jun; Sun Lian-Feng

Source:
CHINESE PHYSICS B 19 (6): Art. No. 066101 JUN 2010

Language:
English

Document Type:
Article

Author Keywords:
single-walled carbon nanotube; water; energy conversion

KeyWords Plus:
FLOW

Abstract:
In this paper, we report that an electromotive force (EMF) can be induced in a rope of aligned single-walled carbon nanotubes (SWNTs) when water droplets fall on this rope. The magnitude of this EMF depends sensitively on the slant angle of the SWNTs. Most interestingly, both the magnitude and the direction of the induced EFM can be modulated by applying a current to the SWNTs. The concepts of electrical slip and no-slip are proposed and can be quantitatively described by "electrical slip resistance". This kind of generator does not need any magnet, rotor, etc and shows quite a different operating mechanism and design compared with a conventional large scale hydroelectric power generator.

Reprint Address:
Sun, LF, Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China.

Research Institution addresses:
[Liu Ji; Zheng Kai-Hong; Liu Zheng; Hu Li-Jun; Sun Lian-Feng] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China; [Liu Ji; Liu Zheng; Hu Li-Jun] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

E-mail Address:
slf@nanoctr.cn

Cited References:
CHESNOKOV SA, 1999, PHYS REV LETT, V82, P343.
COHEN AE, 2003, SCIENCE, V300, P1235.
COLLINS PG, 2000, SCIENCE, V287, P1801.
EBBESEN TW, 1996, NATURE, V382, P54.
GHOSH S, 2003, SCIENCE, V299, P1042, DOI 10.1126/science.1079080.
GHOSH S, 2003, SCIENCE, V300, P1235.
GHOSH S, 2004, PHYS REV B, V70, ARTN 205423.
HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298.
KRAL P, 2001, PHYS REV LETT, V86, P131.
LIU GT, 2008, NANO LETT, V8, P1071, DOI 10.1021/nl073007o.
LIU JW, 2007, J APPL PHYS, V101, ARTN 064312.
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PARADISO JA, 2005, IEEE PERVAS COMPUT, V4, P18.
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ZHOU XY, 2007, CHINESE PHYS, V16, P335.

Cited Reference Count:
26

Times Cited:
0

Publisher:
IOP PUBLISHING LTD; DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND

Subject Category:
Physics, Multidisciplinary

ISSN:
1674-1056

DOI:
10.1088/1674-1056/19/6/066101

IDS Number:
608VG

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Title:
Direct transition of potential of water droplets to electric energy using aligned single-walled carbon nanotubes

Authors:
Liu, J; Zheng, KH; Liu, Z; Hu, LJ; Sun, LF

Author Full Names:
Liu Ji; Zheng Kai-Hong; Liu Zheng; Hu Li-Jun; Sun Lian-Feng

Source:
CHINESE PHYSICS B 19 (6): Art. No. 066101 JUN 2010

Language:
English

Document Type:
Article

Author Keywords:
single-walled carbon nanotube; water; energy conversion

KeyWords Plus:
FLOW

Abstract:
In this paper, we report that an electromotive force (EMF) can be induced in a rope of aligned single-walled carbon nanotubes (SWNTs) when water droplets fall on this rope. The magnitude of this EMF depends sensitively on the slant angle of the SWNTs. Most interestingly, both the magnitude and the direction of the induced EFM can be modulated by applying a current to the SWNTs. The concepts of electrical slip and no-slip are proposed and can be quantitatively described by "electrical slip resistance". This kind of generator does not need any magnet, rotor, etc and shows quite a different operating mechanism and design compared with a conventional large scale hydroelectric power generator.

Reprint Address:
Sun, LF, Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China.

Research Institution addresses:
[Liu Ji; Zheng Kai-Hong; Liu Zheng; Hu Li-Jun; Sun Lian-Feng] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China; [Liu Ji; Liu Zheng; Hu Li-Jun] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

E-mail Address:
slf@nanoctr.cn

Cited References:
CHESNOKOV SA, 1999, PHYS REV LETT, V82, P343.
COHEN AE, 2003, SCIENCE, V300, P1235.
COLLINS PG, 2000, SCIENCE, V287, P1801.
EBBESEN TW, 1996, NATURE, V382, P54.
GHOSH S, 2003, SCIENCE, V299, P1042, DOI 10.1126/science.1079080.
GHOSH S, 2003, SCIENCE, V300, P1235.
GHOSH S, 2004, PHYS REV B, V70, ARTN 205423.
HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298.
KRAL P, 2001, PHYS REV LETT, V86, P131.
LIU GT, 2008, NANO LETT, V8, P1071, DOI 10.1021/nl073007o.
LIU JW, 2007, J APPL PHYS, V101, ARTN 064312.
MAJUMDER M, 2005, NATURE, V438, P44, DOI 10.1038/43844a.
PARADISO JA, 2005, IEEE PERVAS COMPUT, V4, P18.
PERSSON BNJ, 2006, PHYS REV B, V69, UNSP 235410.
QIN Y, 2008, NATURE, V451, P809, DOI 10.1038/nature06601.
SOOD AK, 2004, PHYS REV LETT, V93, ARTN 086601.
THOMPSON PA, 1997, NATURE, V389, P360.
TIAN BZ, 2007, NATURE, V449, P885, DOI 10.1038/nature06181.
WANG G, 2007, IET NANOBIOTECHNOL, V1, P102, DOI 10.1049/iet-nbt:20070011.
WANG Y, 2003, CHINESE PHYS, V12, P1007.
WANG ZL, 2006, SCIENCE, V312, P242, DOI 10.1126/science.1124005.
XU Z, 2005, APPL PHYS LETT, V87, ARTN 163106.
YANG RS, 2009, NAT NANOTECHNOL, V4, P34, DOI 10.1038/NNANO.2008.314.
ZHANG Y, 2008, CHINESE PHYS B, V17, P1881.
ZHAO YC, 2008, ADV MATER, V20, P1772, DOI 10.1002/adma.200702956.
ZHOU XY, 2007, CHINESE PHYS, V16, P335.

Cited Reference Count:
26

Times Cited:
0

Publisher:
IOP PUBLISHING LTD; DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND

Subject Category:
Physics, Multidisciplinary

ISSN:
1674-1056

DOI:
10.1088/1674-1056/19/6/066101

IDS Number:
608VG

========================================================================

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Title:
Raman spectroelectrochemistry of a single-wall carbon nanotube bundle

Authors:
Zhang, L; Liao, V; Yu, ZH

Author Full Names:
Zhang, Li; Liao, Virginia; Yu, Zhonghua

Source:
CARBON 48 (9): 2582-2589 AUG 2010

Language:
English

Document Type:
Article

KeyWords Plus:
CHEMICAL-VAPOR-DEPOSITION; FIELD-EFFECT TRANSISTORS; ELECTRONIC-STRUCTURE; CHARGE-TRANSFER; SPECTROSCOPY; RENORMALIZATION; SCATTERING; DIAMETER; SENSORS; GROWTH

Abstract:
Raman microscopy and spectroelectrochemistry with polymer electrolyte gating is developed to study the effect of charging on Raman spectra of individual single-wall carbon nanotubes (SWCNTs) and bundles. The Raman spectra of a small bundle, consisting of well-separated features from a metallic and a semiconducting SWCNT, have been obtained at different electrochemical charging levels. The broad Fano peak of the metallic SWCNT exhibits an appreciable frequency upshift and simultaneous line narrowing when the charging level, either positive or negative, is increased, in agreement with the presence of a Kohn anomaly in metallic SWCNTs. The radial breathing mode of the metallic tube also shows a similar but much weaker dependence on the charging potential. While the G mode frequencies of the semiconducting SWCNT also increase with the increasing charging level, the magnitude of such change is much smaller than in the metallic SWCNT. At high negative charging potentials the G(-) !
peak of the semiconducting SWCNT exhibits a larger upshift than its G(+) peak, leading to the observation of merging of these two peaks. However, both G(+) and G(-) peaks of the semiconducting SWCNT become broader at high charging levels, which are not predicted from previous theoretical studies. (C) 2010 Elsevier Ltd. All rights reserved.

Reprint Address:
Yu, ZH, CUNY City Coll, Dept Chem, New York, NY 10031 USA.

Research Institution addresses:
[Zhang, Li; Liao, Virginia; Yu, Zhonghua] CUNY City Coll, Dept Chem, New York, NY 10031 USA

E-mail Address:
zyu@sci.ccny.cuny.edu

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Cited Reference Count:
58

Times Cited:
0

Publisher:
PERGAMON-ELSEVIER SCIENCE LTD; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

Subject Category:
Chemistry, Physical; Materials Science, Multidisciplinary

ISSN:
0008-6223

DOI:
10.1016/j.carbon.2010.03.061

IDS Number:
608LK

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ISI Web of Knowledge Alert - Hummer, G

ISI Web of Knowledge Citation Alert

Cited Article: Hummer, G. Water conduction through the hydrophobic channel of a carbon nanotube
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Confined Polar Mixtures within Cylindrical Nanocavities

Authors:
Rodriguez, J; Elola, MD; Laria, D

Author Full Names:
Rodriguez, Javier; Dolores Elola, M.; Laria, Daniel

Source:
JOURNAL OF PHYSICAL CHEMISTRY B 114 (23): 7900-7908 JUN 17 2010

Language:
English

Document Type:
Article

KeyWords Plus:
MOLECULAR-DYNAMICS SIMULATIONS; WATER-ACETONITRILE MIXTURES; BINARY-LIQUID MIXTURES; CARBON NANOTUBES; SILICA-NANOCHANNELS; ULTRAFAST DYNAMICS; SOLVATION DYNAMICS; PHASE-SEPARATION; REVERSE MICELLES; SURFACE POLARITY

Abstract:
Using molecular dynamics experiments, we have extended our previous analysis of equimolar mixtures of water and acetonitrile confined between silica walls [J. Phys. Chem. B 2009, 113, 12744] to examine similar solutions trapped within carbon nanotubes and cylindrical silica pores. Two different carbon tube sizes were investigated, (8,8) tubes, with radius R-cnt = 0.55 nm, and (16,16) ones, with R-cnt = 1.1 nm. In the narrowest tubes, we found that the cylindrical cavity is filled exclusively by acetonitrile; as the radius of the tube reaches similar to 1 nm, water begins to get incorporated within the inner cavities. In (16,16) tubes, the analysis of global and local concentration fluctuations shows a net increment of the global acetonitrile concentration; in addition, the aprotic solvent is also the prevailing species at the vicinity of the tube walls. Mixtures confined within silica nanopores of radius similar to 1.5 nm were also investigated. Three pores, differing in the!
effective wall/solvent interactions, were analyzed, (i) a first class, in which dispersive forces prevail (hydrophobic cavities), (ii) a second type, where oxygen sites at the pore walls are transformed into polar silanol groups (hydrophilic cavities), and (iii) finally, an intermediate scenario, in which 60% of the OH groups are replaced by mobile trimethylsilyl groups. Within the different pores, we found clear distinctions between the solvent layers that lie in close contact with the silica substrate and those with more central locations. Dynamical modes of the confined liquid phases were investigated in terms of diffusive and rotational time correlation functions. Compared to bulk results, the characteristic time scales describing different solvent motions exhibit significant increments. In carbon nanotubes, the most prominent modifications operate in the narrower tubes, where translations and rotations become severely hindered. In silica nanopores, the manifestations !
of the overall retardations are more dramatic for solvent spec!
ies lyin
g at the vicinity of trimethylsilyl groups.

Reprint Address:
Laria, D, Comis Nacl Energia Atom, Dept Fis, Ave Libertador 8250, RA-1429 Buenos Aires, DF, Argentina.

Research Institution addresses:
[Rodriguez, Javier; Dolores Elola, M.; Laria, Daniel] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina; [Rodriguez, Javier] UNSAM, ECyT, RA-1650 San Martin, Buenos Aires, Argentina; [Laria, Daniel] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim Fis & INQUIMAE, RA-1428 Buenos Aires, DF, Argentina

E-mail Address:
dhlaria@cnea.gov.ar

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76

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Physical

ISSN:
1520-6106

DOI:
10.1021/jp101836b

IDS Number:
607DV

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ISI Web of Knowledge Alert - Zhao, Y

ISI Web of Knowledge Citation Alert

Cited Article: Zhao, Y. Individual water-filled single-walled carbon nanotubes as hydroelectric power converters
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Direct transition of potential of water droplets to electric energy using aligned single-walled carbon nanotubes

Authors:
Liu, J; Zheng, KH; Liu, Z; Hu, LJ; Sun, LF

Author Full Names:
Liu Ji; Zheng Kai-Hong; Liu Zheng; Hu Li-Jun; Sun Lian-Feng

Source:
CHINESE PHYSICS B 19 (6): Art. No. 066101 JUN 2010

Language:
English

Document Type:
Article

Author Keywords:
single-walled carbon nanotube; water; energy conversion

KeyWords Plus:
FLOW

Abstract:
In this paper, we report that an electromotive force (EMF) can be induced in a rope of aligned single-walled carbon nanotubes (SWNTs) when water droplets fall on this rope. The magnitude of this EMF depends sensitively on the slant angle of the SWNTs. Most interestingly, both the magnitude and the direction of the induced EFM can be modulated by applying a current to the SWNTs. The concepts of electrical slip and no-slip are proposed and can be quantitatively described by "electrical slip resistance". This kind of generator does not need any magnet, rotor, etc and shows quite a different operating mechanism and design compared with a conventional large scale hydroelectric power generator.

Reprint Address:
Sun, LF, Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China.

Research Institution addresses:
[Liu Ji; Zheng Kai-Hong; Liu Zheng; Hu Li-Jun; Sun Lian-Feng] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China; [Liu Ji; Liu Zheng; Hu Li-Jun] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

E-mail Address:
slf@nanoctr.cn

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Cited Reference Count:
26

Times Cited:
0

Publisher:
IOP PUBLISHING LTD; DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND

Subject Category:
Physics, Multidisciplinary

ISSN:
1674-1056

DOI:
10.1088/1674-1056/19/6/066101

IDS Number:
608VG

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