Friday, August 13, 2010

ISI Web of Knowledge Alert - Ghosh, S

ISI Web of Knowledge Citation Alert

Cited Article: Ghosh, S. Carbon nanotube flow sensors
Alert Expires: 09 NOV 2010
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Sensors Based On Carbon Nanotubes and Their Applications: A Review

Authors:
Varghese, SH; Nair, R; Nair, BG; Hanajiri, T; Maekawa, T; Yoshida, Y; Kumar, DS

Author Full Names:
Varghese, Saino Hanna; Nair, Remya; Nair, Baiju G.; Hanajiri, T.; Maekawa, T.; Yoshida, Y.; Kumar, D. Sakthi

Source:
CURRENT NANOSCIENCE 6 (4): 331-346 AUG 2010

Language:
English

Document Type:
Article

Author Keywords:
Sensors; single wall carbon nanotubes; multi wall carbon nanotubes; biosensors; chemical sensors; nanomechanical resonators

KeyWords Plus:
FIELD-EFFECT TRANSISTORS; NONENZYMATIC GLUCOSE SENSOR; LOW-POTENTIAL DETECTION; MODIFIED ELECTRODE; ELECTROCHEMICAL DETECTION; NITRIC-OXIDE; DNA HYBRIDIZATION; CHEMICAL SENSORS; ROOM-TEMPERATURE; GAS-DETECTION

Abstract:
Sensors play a significant role in everyday life. Nowadays, there has been a strong demand for highly selective, sensitive, responsive, stable and cost effective sensors. As a result, research emphasis is on developing new sensing materials and technologies. Carbon nanotubes (CNTs) have many distinct properties that may be exploited to develop next generation of sensors. They exhibit extraordinary strength and unique combination of excellent mechanical, electrical, thermal, optical and electrochemical properties even in its small dimension nature, which has generated increasing interest in the application of CNTs as sensors. The main thrust of this review is to highlight the present and future research and development work in the area of CNT based sensors. Different types of sensors such as biosensors, chemical sensors, mass sensors, temperature sensors, strain sensors and pressure sensors based on CNTs are also discussed in detail. This manuscript concludes with an outline !
of the advantages of these CNT based sensors for real-world applications. This review aims to act as a reference source for researchers to help them in developing new applications of sensors based on CNTs.

Reprint Address:
Kumar, DS, Toyo Univ, Grad Sch Interdisciplinary New Sci, Bio Nano Elect Res Ctr, Kawagoe, Saitama 3508585, Japan.

Research Institution addresses:
[Varghese, Saino Hanna; Nair, Remya; Nair, Baiju G.; Hanajiri, T.; Maekawa, T.; Yoshida, Y.; Kumar, D. Sakthi] Toyo Univ, Grad Sch Interdisciplinary New Sci, Bio Nano Elect Res Ctr, Kawagoe, Saitama 3508585, Japan

E-mail Address:
sakthi@toyonet.toyo.ac.jp

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Cited Reference Count:
243

Times Cited:
0

Publisher:
BENTHAM SCIENCE PUBL LTD; EXECUTIVE STE Y26, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATES

Subject Category:
Biotechnology & Applied Microbiology; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary

ISSN:
1573-4137

IDS Number:
633MJ

========================================================================

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Title:
Nanomaterials in the Construction Industry: A Review of Their Applications and Environmental Health and Safety Considerations

Authors:
Lee, J; Mahendra, S; Alvarez, PJJ

Author Full Names:
Lee, Jaesang; Mahendra, Shaily; Alvarez, Pedro J. J.

Source:
ACS NANO 4 (7): 3580-3590 JUL 2010

Language:
English

Document Type:
Review

Author Keywords:
concrete; windows; sensor; exposure; bioavailability; toxicity; oxidative stress; industrial ecology; risk assessment; labeling

KeyWords Plus:
FULLERENE WATER SUSPENSIONS; QUANTUM-DOT NANOPARTICLES; CARBON NANOTUBES; MANUFACTURED NANOMATERIALS; ANTIMICROBIAL ACTIVITY; DEMOLITION WASTE; ANTIBACTERIAL ACTIVITY; COPPER NANOPARTICLES; SURFACE MODIFICATION; COMPARATIVE TOXICITY

Abstract:
The extraordinary chemical and physical properties of materials at the nanometer scale enable novel applications ranging from structural strength enhancement and energy conservation to antimicrobial properties and self-cleaning surfaces. Consequently, manufactured nanomaterials (MNMs) and nanocomposites are being considered for various uses in the construction and related infrastructure industries. To achieve environmentally responsible nanotechnology in construction, it is important to consider the lifecycle impacts of MNMs on the health of construction workers and dwellers, as well as unintended environmental effects at all stages of manufacturing, construction, use, demolition, and disposal. Here, we review state-of-the-art applications of MNMs that improve conventional construction materials, suggest likely environmental release scenarios, and summarize potential adverse biological and toxicological effects and their mitigation. Aligned with multidisciplinary assessment !
of the environmental implications of emerging technologies, this review seeks to promote awareness of potential benefits of MNMs in construction and stimulate the development of guidelines to regulate their use and disposal to mitigate potential adverse effects on human and environmental health.

Reprint Address:
Alvarez, PJJ, Rice Univ, Dept Civil & Environm Engn, Houston, TX 77005 USA.

Research Institution addresses:
[Lee, Jaesang; Alvarez, Pedro J. J.] Rice Univ, Dept Civil & Environm Engn, Houston, TX 77005 USA; [Mahendra, Shaily] Univ Calif Los Angeles, Dept Civil & Environm Engn, Los Angeles, CA 90095 USA

E-mail Address:
alvarez@rice.edu

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Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary

ISSN:
1936-0851

DOI:
10.1021/nn100866w

IDS Number:
631RG

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Cited Article: Hummer, G. Water conduction through the hydrophobic channel of a carbon nanotube
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Title:
Biased transportations in a spatially asymmetric system at the nano-scale under thermal noise

Authors:
Wan, RZ; Fang, HP

Author Full Names:
Wan RongZheng; Fang HaiPing

Source:
SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY 53 (8): 1565-1567 AUG 2010

Language:
English

Document Type:
Article

Author Keywords:
ratchet effect; nano-scale; thermal noise

KeyWords Plus:
WATER; CONDUCTION; CHANNEL

Abstract:
Under the theory of ratchet effect for meso- and macro-scale systems, the additional perturbation with a long time correlation and the breaking of spatial inversion symmetry are two main ingredients to bring unidirected transportations. With the help of a simple model system, we show that a spatially asymmetric system of the nano-scale length may induce biased transportations under thermal noise.

Reprint Address:
Fang, HP, Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.

Research Institution addresses:
[Wan RongZheng; Fang HaiPing] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China

E-mail Address:
fanghaiping@sinap.ac.cn

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Cited Reference Count:
13

Times Cited:
0

Publisher:
SCIENCE CHINA PRESS; 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA

Subject Category:
Physics, Multidisciplinary

ISSN:
1674-7348

DOI:
10.1007/s11433-010-4044-8

IDS Number:
633CN

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Title:
Electrokinetics at Aqueous Interfaces without Mobile Charges

Authors:
Bonthuis, DJ; Horinek, D; Bocquet, L; Netz, RR

Author Full Names:
Bonthuis, Douwe Jan; Horinek, Dominik; Bocquet, Lyderic; Netz, Roland R.

Source:
LANGMUIR 26 (15): 12614-12625 AUG 3 2010

Language:
English

Document Type:
Article

KeyWords Plus:
CARBON NANOTUBES; HYDROPHILIC SURFACES; NEAT WATER; TRANSPORT; FLUID; VISCOSITY; STRESS; PUMP; MICROFLUIDICS; HYDRODYNAMICS

Abstract:
We theoretically consider the possibility of using electric fields in aqueous channels of cylindrical and planar geometry to induce transport in the absence of mobile ionic charges. Using the Navier-Stokes equation, generalized to include the effects of water spinning, dipole orientation and relaxation, we show analytically that pumping of a dipolar liquid through an uncharged hydrophobic channel can be achieved by injecting torque into the liquid, based on the coupling between molecular spinning and fluid vorticity. This is possible using rotating electric fields and suitably chosen interfacial boundary conditions or transiently by suddenly switching on a homogeneous electric field. A static electric field, however, does not induce a steady state flow in channels, irrespective of the geometry. Using molecular dynamics (MD) simulations, we confirm that static fields do not lead to any pumping, in contrast to earlier publications. The pumping observed in MD simulations of car!
bon nanotubes and oil droplets in a static electric field is tracked down to an imprudent implementation of Leonard-Jones interaction truncation schemes.

Reprint Address:
Bonthuis, DJ, Tech Univ Munich, Dept Phys, D-85748 Garching, Germany.

Research Institution addresses:
[Bonthuis, Douwe Jan; Horinek, Dominik; Bocquet, Lyderic; Netz, Roland R.] Tech Univ Munich, Dept Phys, D-85748 Garching, Germany; [Bocquet, Lyderic] Univ Lyon 1, CNRS, Lab PMCN, UMR 5586, F-69622 Villeurbanne, France

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JOSEPH S, 2008, PHYS REV LETT, V101, ARTN 064502.
KIM D, 2009, J COLLOID INTERF SCI, V330, P194, DOI 10.1016/j.jcis.2008.10.029.
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Cited Reference Count:
44

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary

ISSN:
0743-7463

DOI:
10.1021/la9034535

IDS Number:
631NI

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Title:
Water Chains in Hydrophobic Crystal Channels: Nanoporous Materials as Supramolecular Analogues of Carbon Nanotubes

Authors:
Natarajan, R; Charmant, JPH; Orpen, AG; Davis, AP

Author Full Names:
Natarajan, Ramalingam; Charmant, Jonathan P. H.; Orpen, A. Guy; Davis, Anthony P.

Source:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 49 (30): 5125-5129 2010

Language:
English

Document Type:
Article

Author Keywords:
crystal engineering; hydrogen bonding; hydrophobic effect; supramolecular chemistry; water chains

KeyWords Plus:
TRANSPORT; MEMBRANES

Reprint Address:
Davis, AP, Univ Bristol, Sch Chem, Cantocks Close, Bristol BS8 1TS, Avon, England.

Research Institution addresses:
[Natarajan, Ramalingam; Charmant, Jonathan P. H.; Orpen, A. Guy; Davis, Anthony P.] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

E-mail Address:
anthony.davis@bristol.ac.uk

Cited References:
AGRE P, 2004, ANGEW CHEM, V116, P4377.
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SISSON AL, 2005, ANGEW CHEM INT EDIT, V44, P6878, DOI 10.1002/anie.200502330.
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WANG ZK, 2007, NANO LETT, V7, P697, DOI 10.1021/nl062853g.

Cited Reference Count:
19

Times Cited:
0

Publisher:
WILEY-V C H VERLAG GMBH; PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY

Subject Category:
Chemistry, Multidisciplinary

ISSN:
1433-7851

DOI:
10.1002/anie.201002418

IDS Number:
632NT

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ISI Web of Knowledge Alert - Thompson, P

ISI Web of Knowledge Citation Alert

Cited Article: Thompson, P. A general boundary condition for liquid flow at solid surfaces
Alert Expires: 09 NOV 2010
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Multi-scale computational modelling of flow and heat transfer

Authors:
Drikakis, D; Asproulis, N

Author Full Names:
Drikakis, Dimitris; Asproulis, Nikolaos

Source:
INTERNATIONAL JOURNAL OF NUMERICAL METHODS FOR HEAT & FLUID FLOW 20 (5): 517-528 2010

Language:
English

Document Type:
Proceedings Paper

Author Keywords:
Modelling; Heat transfer; Fluid dynamics; Flow; Microscopy; Gas flow

KeyWords Plus:
PARTICLE-CONTINUUM SIMULATIONS; MOLECULAR-DYNAMICS SIMULATION; SURFACE-ROUGHNESS; FLUID-FLOW; GAS-FLOW

Abstract:
Purpose - The purpose of this paper is to present different approaches for applying macroscopic boundary conditions in hybrid multiscale modelling.
Design/methodology/approach - Molecular dynamics (MD) was employed for the microscopic simulations. The continuum boundary conditions were applied either through rescaling of atomistic velocities or resampling based on velocity distribution functions.
Findings - The methods have been tested for various fluid flows with heat transfer scenarios. The selection of the most suitable method is not a trivial task and depends on a number of factors such as accuracy requirements and availability of computational resource.
Originality/value - The applicability of the methods has been assessed for liquid and gas flows. Specific parameters that affect their accuracy and efficiency have been identified. The effects of these parameters on the accuracy and efficiency of the simulations are investigated. The study provides knowledge regarding the development and application of boundary conditions in multiscale computational frameworks.

Reprint Address:
Drikakis, D, Cranfield Univ, Dept Aerosp, Fluid Mech & Computat Sci Grp, Cranfield MK43 0AL, Beds, England.

Research Institution addresses:
[Drikakis, Dimitris; Asproulis, Nikolaos] Cranfield Univ, Dept Aerosp, Fluid Mech & Computat Sci Grp, Cranfield MK43 0AL, Beds, England

E-mail Address:
d.drikakis@cranfield.ac.uk

Cited References:
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YANG SC, 2006, MICROFLUID NANOFLUID, V2, P501, DOI 10.1007/s10404-006-0096-5.

Cited Reference Count:
35

Times Cited:
1

Publisher:
EMERALD GROUP PUBLISHING LIMITED; HOWARD HOUSE, WAGON LANE, BINGLEY BD16 1WA, W YORKSHIRE, ENGLAND

Subject Category:
Thermodynamics; Mathematics, Interdisciplinary Applications; Mechanics

ISSN:
0961-5539

DOI:
10.1108/09615531011048222

IDS Number:
632QL

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Title:
Numerical Simulation and Experimental Study of Polymer Micro Extrusion Flow

Authors:
Zhao, DY; Jin, YF; Wang, MJ; Li, K; Song, MC

Author Full Names:
Zhao, Danyang; Jin, Yifei; Wang, Minjie; Li, Kai; Song, Mancang

Source:
2009 IEEE INTERNATIONAL CONFERENCE ON MECHATRONICS AND AUTOMATION, VOLS 1-7, CONFERENCE PROCEEDINGS : 3155-3160 2009

Language:
English

Document Type:
Proceedings Paper

Author Keywords:
micro extrusion; micro scale effect; rheology characteristics; lumen structure; uniformity

KeyWords Plus:
RHEOLOGICAL BEHAVIOR; CHANNELS; FLUIDS

Abstract:
The uniformity of polymer melt flow in micro extrusion die determines the quality of products directly. It is the base of extrusion die design. According to rheology testing theory and with the help of capillary rheometer, the reasonable extrusion parameters have been achieved. The comparative micro scale viscosity model is built based on Kelvin-Voigt constitutive equation and the wall slip model is built based on Navier slip law. The extrusion of double-lumen is taken for example. By use of both numerical simulation and orthogonal experiment, the effects of main structure parameters on flow uniformity are studied. The conclusions show that shunting angle affects the uniformity most, then length of center stereotyping part, compression angle and compression ratio. Meanwhile, the best lumen structure parameters are determined. After that, double-lumen catheter die is fabricated by precision machining technology. The results of experiment validate the correctness and validity !
of numerical simulation for polymer micro extrusion flow.

Reprint Address:
Zhao, DY, Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian, Liaoning Prov, Peoples R China.

Research Institution addresses:
[Zhao, Danyang; Jin, Yifei; Wang, Minjie; Li, Kai; Song, Mancang] Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian, Liaoning Prov, Peoples R China

E-mail Address:
danyangz@163.com

Cited References:
CHEN CS, 2008, J EUROPEAN POLYM, V43, P1891.
CHEN SC, 2005, INT COMMUN HEAT MASS, V32, P501, DOI 10.1016/j.icheatmasstransfer.2004.07.004.
CHIEN RD, 2005, J MICROMECH MICROENG, V15, P1389, DOI 10.1088/0960-1317/15/8/003.
ERINGEN AC, 1995, INT J ENG SCI, V33, P2297.
GRANICK S, 2003, NAT MATER, V2, P221.
MUNSTEDT H, 2000, J RHEOL, V44, P413.
THOMPSON PA, 1997, NATURE, V389, P360.

Cited Reference Count:
7

Times Cited:
0

Publisher:
IEEE; 345 E 47TH ST, NEW YORK, NY 10017 USA

IDS Number:
BPW54

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ISI Web of Knowledge Alert - Majumder M

ISI Web of Knowledge Citation Alert

Cited Article: Majumder M. Nanoscale hydrodynamics - Enhanced flow in carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
========================================================================
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Title:
Diverse corrugation pattern in radially shrinking carbon nanotubes

Authors:
Shima, H; Sato, M; Iiboshi, K; Ghosh, S; Arroyo, M

Author Full Names:
Shima, Hiroyuki; Sato, Motohiro; Iiboshi, Kohtaroh; Ghosh, Susanta; Arroyo, Marino

Source:
PHYSICAL REVIEW B 82 (8): Art. No. 085401 AUG 2 2010

Language:
English

Document Type:
Article

KeyWords Plus:
ELECTROCHEMICAL STORAGE; HYDROSTATIC-PRESSURE; DIAMOND FORMATION; ELECTRON-BEAM; SINGLE-WALL; ENERGY; DEFORMATION; FLEXIBILITY; TRANSITION; ONIONS

Abstract:
Stable cross sections of multiwalled carbon nanotubes subjected to electron-beam irradiation are investigated in the realm of the continuum mechanics approximation. The self-healing nature of sp(2) graphitic sheets implies that selective irradiation of the outermost walls causes their radial shrinkage with the remaining inner walls undamaged. The shrinking walls exert high pressure on the interior part of nanotubes, yielding a wide variety of radial-corrugation patterns (i.e., circumferentially wrinkling structures) in the cross section. All corrugation patterns can be classified into two deformation phases for which the corrugation amplitudes of the innermost wall differ significantly.

Reprint Address:
Shima, H, Hokkaido Univ, Div Appl Phys, Fac Engn, Sapporo, Hokkaido 0608628, Japan.

Research Institution addresses:
[Shima, Hiroyuki] Hokkaido Univ, Div Appl Phys, Fac Engn, Sapporo, Hokkaido 0608628, Japan; [Shima, Hiroyuki; Ghosh, Susanta; Arroyo, Marino] Univ Politecn Cataluna, Dept Appl Math 3, LaCaN, ES-08034 Barcelona, Spain; [Sato, Motohiro] Hokkaido Univ, Div Socioenvironm Engn, Fac Engn, Sapporo, Hokkaido 0608628, Japan; [Iiboshi, Kohtaroh] Hokkaido Univ, Div Socioenvironm Engn, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan

E-mail Address:
shima@eng.hokudai.ac.jp

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Cited Reference Count:
64

Times Cited:
0

Publisher:
AMER PHYSICAL SOC; ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA

Subject Category:
Physics, Condensed Matter

ISSN:
1098-0121

DOI:
10.1103/PhysRevB.82.085401

IDS Number:
633FU

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Title:
Electrokinetics at Aqueous Interfaces without Mobile Charges

Authors:
Bonthuis, DJ; Horinek, D; Bocquet, L; Netz, RR

Author Full Names:
Bonthuis, Douwe Jan; Horinek, Dominik; Bocquet, Lyderic; Netz, Roland R.

Source:
LANGMUIR 26 (15): 12614-12625 AUG 3 2010

Language:
English

Document Type:
Article

KeyWords Plus:
CARBON NANOTUBES; HYDROPHILIC SURFACES; NEAT WATER; TRANSPORT; FLUID; VISCOSITY; STRESS; PUMP; MICROFLUIDICS; HYDRODYNAMICS

Abstract:
We theoretically consider the possibility of using electric fields in aqueous channels of cylindrical and planar geometry to induce transport in the absence of mobile ionic charges. Using the Navier-Stokes equation, generalized to include the effects of water spinning, dipole orientation and relaxation, we show analytically that pumping of a dipolar liquid through an uncharged hydrophobic channel can be achieved by injecting torque into the liquid, based on the coupling between molecular spinning and fluid vorticity. This is possible using rotating electric fields and suitably chosen interfacial boundary conditions or transiently by suddenly switching on a homogeneous electric field. A static electric field, however, does not induce a steady state flow in channels, irrespective of the geometry. Using molecular dynamics (MD) simulations, we confirm that static fields do not lead to any pumping, in contrast to earlier publications. The pumping observed in MD simulations of car!
bon nanotubes and oil droplets in a static electric field is tracked down to an imprudent implementation of Leonard-Jones interaction truncation schemes.

Reprint Address:
Bonthuis, DJ, Tech Univ Munich, Dept Phys, D-85748 Garching, Germany.

Research Institution addresses:
[Bonthuis, Douwe Jan; Horinek, Dominik; Bocquet, Lyderic; Netz, Roland R.] Tech Univ Munich, Dept Phys, D-85748 Garching, Germany; [Bocquet, Lyderic] Univ Lyon 1, CNRS, Lab PMCN, UMR 5586, F-69622 Villeurbanne, France

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44

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary

ISSN:
0743-7463

DOI:
10.1021/la9034535

IDS Number:
631NI

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ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 09 NOV 2010
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AU Natarajan, R
Charmant, JPH
Orpen, AG
Davis, AP
AF Natarajan, Ramalingam
Charmant, Jonathan P. H.
Orpen, A. Guy
Davis, Anthony P.
TI Water Chains in Hydrophobic Crystal Channels: Nanoporous Materials as
Supramolecular Analogues of Carbon Nanotubes
SO ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
LA English
DT Article
DE crystal engineering; hydrogen bonding; hydrophobic effect;
supramolecular chemistry; water chains
ID TRANSPORT; MEMBRANES
C1 [Natarajan, Ramalingam; Charmant, Jonathan P. H.; Orpen, A. Guy; Davis, Anthony P.] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England.
RP Davis, AP, Univ Bristol, Sch Chem, Cantocks Close, Bristol BS8 1TS,
Avon, England.
EM anthony.davis@bristol.ac.uk
CR AGRE P, 2004, ANGEW CHEM, V116, P4377
FORNASIERO F, 2008, P NATL ACAD SCI USA, V105, P17250, DOI
10.1073/pnas.0710437105
HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298
HOLT JK, 2009, ADV MATER, V21, P3542, DOI 10.1002/adma.200900867
HUMMER G, 2001, NATURE, V414, P188
KALRA A, 2003, P NATL ACAD SCI USA, V100, P10175
KOGA K, 2001, NATURE, V412, P802
MASCAL M, 2006, ANGEW CHEM INT EDIT, V45, P32, DOI
10.1002/anie.200501839
RAGHAVENDER US, 2009, J AM CHEM SOC, V131, P15130, DOI 10.1021/ja9038906
RAGHAVENDER US, 2010, J AM CHEM SOC, V132, P1075, DOI 10.1021/ja9083978
SANSOM MSP, 2001, NATURE, V414, P156
SHANNON MA, 2008, NATURE, V452, P301, DOI 10.1038/nature06599
SISSON AL, 2005, ANGEW CHEM INT EDIT, V44, P6878, DOI
10.1002/anie.200502330
SISSON AL, 2005, ANGEW CHEM, V117, P7038
SUZUKI S, 1992, SCIENCE, V257, P942
TAKAIWA D, 2008, P NATL ACAD SCI USA, V105, P39, DOI
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WANG L, 2009, J PHYS CHEM C, V113, P5368, DOI 10.1021/jp808873r
WANG ZK, 2007, NANO LETT, V7, P697, DOI 10.1021/nl062853g
NR 19
TC 0
PU WILEY-V C H VERLAG GMBH; PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY
SN 1433-7851
DI 10.1002/anie.201002418
VL 49
IS 30
BP 5125
EP 5129
SC Chemistry, Multidisciplinary
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Friday, August 6, 2010

ISI Web of Knowledge Alert - Hummer, G

ISI Web of Knowledge Citation Alert

Cited Article: Hummer, G. Water conduction through the hydrophobic channel of a carbon nanotube
Alert Expires: 09 NOV 2010
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Title:
Giant Electrorheological Effect: A Microscopic Mechanism

Authors:
Chen, SY; Huang, XX; Van der Vegt, NFA; Wen, WJ; Sheng, P

Author Full Names:
Chen, Shuyu; Huang, Xianxiang; van der Vegt, Nico F. A.; Wen, Weijia; Sheng, Ping

Source:
PHYSICAL REVIEW LETTERS 105 (4): Art. No. 046001 JUL 19 2010

Language:
English

Document Type:
Article

KeyWords Plus:
INDUCED TUNNELING CONDUCTION; MOLECULAR-DYNAMICS; FLUIDS; WATER; UREA; DENATURATION; SIMULATION

Abstract:
Electrorheological fluids constitute a type of colloids that can vary their rheological characteristics upon the application of an electric field. The recently discovered giant electrorheological (GER) effect breaks the upper bound of the traditional ER effect, but a microscopic explanation is still lacking. By using molecular dynamics to simulate the urea-silicone oil mixture trapped in a nanocontact between two polarizable particles, we demonstrate that the electric field can induce the formation of aligned (urea) dipolar filaments that bridge the two boundaries of the nanoscale confinement. This phenomenon is explainable on the basis of a 3D to 1D crossover in urea molecules' microgeometry, realized through the confinement effect provided by the oil chains. The resulting electrical energy density yields an excellent account of the observed GER yield stress variation as a function of the electric field.

Reprint Address:
Sheng, P, Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China.

Research Institution addresses:
[Chen, Shuyu; Huang, Xianxiang; Wen, Weijia; Sheng, Ping] Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China; [Chen, Shuyu; Huang, Xianxiang; Wen, Weijia; Sheng, Ping] Hong Kong Univ Sci & Technol, William Mong Inst Nano Sci & Technol, Kowloon, Hong Kong, Peoples R China; [van der Vegt, Nico F. A.] Tech Univ Darmstadt, Ctr Smart Interfaces, D-64287 Darmstadt, Germany

E-mail Address:
sheng@ust.hk

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Cited Reference Count:
30

Times Cited:
0

Publisher:
AMER PHYSICAL SOC; ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA

Subject Category:
Physics, Multidisciplinary

ISSN:
0031-9007

DOI:
10.1103/PhysRevLett.105.046001

IDS Number:
627UO

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Title:
The effects of the hydrophobic environment on proton mobility in perfluorosulfonic acid systems: an ab initio molecular dynamics study

Authors:
Habenicht, BF; Paddison, SJ; Tuckerman, ME

Author Full Names:
Habenicht, Bradley F.; Paddison, Stephen J.; Tuckerman, Mark E.

Source:
JOURNAL OF MATERIALS CHEMISTRY 20 (30): 6342-6351 2010

Language:
English

Document Type:
Article

KeyWords Plus:
TRANSMISSION INFRARED-SPECTROSCOPY; POLYMER ELECTROLYTE MEMBRANES; FUEL-CELL APPLICATIONS; LIQUID WATER-SURFACE; VIBRATIONAL SPECTROSCOPY; HYDRATED MORPHOLOGIES; EXCHANGE MEMBRANES; NAFION MEMBRANE; TRANSPORT; SIMULATION

Abstract:
Model systems of perfluorosulfonic acid (PFSA) polymers exhibiting regular shaped and idealized channel morphologies were constructed by functionalizing single walled carbon nanotubes (CNTs) with -CF2SO3H groups and adding from 1 to 3H(2)O/SO3H to investigate structural and chemical factors affecting proton dissociation and transport. No a priori assumptions about either the dissociation or hydration of the protons were assumed and extensive ab initio molecular dynamics (AIMD) simulations were performed and subject to analysis. The importance of the hydrophobic environment was assessed by comparing the hydration of the protons both with and without fluorine atoms attached to the CNT walls. The AIMD trajectories showed that dissociation of the acidic proton increased with increasing density of sulfonic acid groups; however, greater densities also brought about trapping of the dissociated proton. The fluorine atoms accepted hydrogen bonds from the water molecules, stabilized h!
ydrogen bonding, and enhanced proton dissociation. The CNT systems without fluorination of the walls exhibited a propensity for the formation of Zundel cations (H5O2+), while the fluorinated systems favoured hydrated structures involving hydronium ions or hydrated H3O+ species depending on the amount of water in the system.

Reprint Address:
Paddison, SJ, Univ Tennessee, Dept Chem & Biomol Engn, Knoxville, TN 37563 USA.

Research Institution addresses:
[Habenicht, Bradley F.; Paddison, Stephen J.] Univ Tennessee, Dept Chem & Biomol Engn, Knoxville, TN 37563 USA; [Tuckerman, Mark E.] NYU, Courant Inst Math Sci, Dept Chem, New York, NY 10003 USA

E-mail Address:
spaddison@utk.edu

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Cited Reference Count:
62

Times Cited:
0

Publisher:
ROYAL SOC CHEMISTRY; THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

Subject Category:
Chemistry, Physical; Materials Science, Multidisciplinary

ISSN:
0959-9428

DOI:
10.1039/c0jm00253d

IDS Number:
628UE

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Title:
Coarse-grained molecular dynamics of tetrameric transmembrane peptide bundles within a lipid bilayer

Authors:
Nguyen, THT; Rao, NZ; Schroeder, WM; Moore, PB

Author Full Names:
Nguyen, Thuy Hien T.; Rao, Niny Z.; Schroeder, William M.; Moore, Preston B.

Source:
CHEMISTRY AND PHYSICS OF LIPIDS 163 (6): 530-537 JUN 2010

Language:
English

Document Type:
Article

Author Keywords:
Ion-channel; LS2 peptide; All-atom; Tetramer bundle; WALP peptide; DMPC bilayer

KeyWords Plus:
SYNTHETIC ION-CHANNEL; INFLUENZA-A VIRUS; MEMBRANE-PROTEINS; COMPUTATIONAL DESIGN; M2 PROTEIN; SIMULATION; MODEL; WATER; DOMAIN; FORMS

Abstract:
The conformations of model transmembrane peptides are studied to understand the structural and dynamical aspects of tetrameric bundles using a series of coarse grain (CG) molecular dynamics (MD) simulations since membrane proteins play a crucial role in cell function. In this work, two different amphipathic models have been constructed using similar hydrophobic/hydrophilic characteristics with two structurally distinct morphologies to evaluate the effect of roughness and hydrophilic topology on the structure of tetrameric bundles, one class that forms an ion-channel and one class that does not. Free energy calculations of typical amphipathic peptide topologies show that using a relatively smooth surface morphology allows for a stable conformation of the tetramer bundle in a diamond formation. However, the model with side chains attached to the core in order to roughen the surface has a stable square tetramer bundle which is consistent with experimental data and all-atom (AA)!
MD simulations. Comparisons of the CG simulations with AA MD simulations are in reasonable agreement with the formation of tetrameric homo-oligomers, partitioning within the lipid bilayer and tilt angle with respect to the bilayer normal. We concluded that a square or diamond shape tetrameric homo-oligomers could be stabilized by rational design of the peptide morphology and topology of the surface, thus allowing us to tune the permeability of the bundle or channel. (C) 2010 Elsevier Ireland Ltd. All rights reserved.

Reprint Address:
Moore, PB, Univ Sci Philadelphia, Dept Chem & Biochem, 600 S 43rd St, Philadelphia, PA 19104 USA.

Research Institution addresses:
[Nguyen, Thuy Hien T.; Schroeder, William M.; Moore, Preston B.] Univ Sci Philadelphia, Dept Chem & Biochem, Philadelphia, PA 19104 USA; [Nguyen, Thuy Hien T.; Schroeder, William M.; Moore, Preston B.] Univ Sci Philadelphia, W Ctr Computat Chem & Drug Design, Philadelphia, PA 19104 USA; [Rao, Niny Z.] Philadelphia Univ, Philadelphia, PA 19144 USA

E-mail Address:
p.moore@usp.edu

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Cited Reference Count:
61

Times Cited:
0

Publisher:
ELSEVIER IRELAND LTD; ELSEVIER HOUSE, BROOKVALE PLAZA, EAST PARK SHANNON, CO, CLARE, 00000, IRELAND

Subject Category:
Biochemistry & Molecular Biology; Biophysics

ISSN:
0009-3084

DOI:
10.1016/j.chemphyslip.2010.04.007

IDS Number:
627IU

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Title:
A REVIEW ON CARBON NANOTUBES IN AN ENVIRONMENTAL PROTECTION AND GREEN ENGINEERING PERSPECTIVE

Authors:
Ong, YT; Ahmad, AL; Zein, SHS; Tan, SH

Author Full Names:
Ong, Yit Thai; Ahmad, Abdul Latif; Zein, Sharif Hussein Sharif; Tan, Soon Huat

Source:
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING 27 (2): 227-242 APR-JUN 2010

Language:
English

Document Type:
Review

Author Keywords:
Carbon nanotubes; Environment; Waste water treatment; Air pollution monitoring; Biotechnologies; Renewable energy; Supercapacitors

KeyWords Plus:
MICROBIAL FUEL-CELLS; HETEROJUNCTION SOLAR-CELLS; HYDROGEN STORAGE CAPACITY; CHEMICAL-VAPOR-DEPOSITION; GLUCOSE/O-2 BIOFUEL CELL; SOLID-PHASE EXTRACTION; LARGE-SCALE PRODUCTION; GAS SENSOR; AQUEOUS-SOLUTION; ROOM-TEMPERATURE

Abstract:
Recent developments in nanotechnologies have helped to benchmark carbon nanotubes (CNTs) as one of the most studied nanomaterials. By taking advantages of CNTs extraordinary physical, chemical and electronic properties, a wide variety of applications has been proposed in various engineering fields. In this short review, the contribution of CNTs is addressed in terms of sustainable environment and green technologies perspective, such as waste water treatment, air pollution monitoring, biotechnologies, renewable energy technologies, supercapacitors and green nanocomposites. Consideration of CNTs for large scale application from the aspect of cost and potential hazards are also discussed. Based on the literature studied, CNTs pose a great potential as a promising material for application in various environmental fields.

Reprint Address:
Tan, SH, Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Pulau Pinang, Malaysia.

Research Institution addresses:
[Ong, Yit Thai; Ahmad, Abdul Latif; Zein, Sharif Hussein Sharif; Tan, Soon Huat] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Pulau Pinang, Malaysia

E-mail Address:
chshtan@eng.usm.my

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0

Publisher:
BRAZILIAN SOC CHEMICAL ENG; RUA LIBERO BADARO 152-11 ANDAR, CEP 01008-90 SAO PAULO, BRAZIL

Subject Category:
Engineering, Chemical

ISSN:
0104-6632

IDS Number:
628ST

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ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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FN ISI Export Format
VR 1.0

PT J
*Record 1 of 1.
L5 <http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS&DestLinkType=FullRecord;UT=000280304600015>
*Order Full Text [ ]
AU Cristadoro, G
Lenci, M
Seri, M
AF Cristadoro, Giampaolo
Lenci, Marco
Seri, Marcello
TI Recurrence for quenched random Lorentz tubes
SO CHAOS
LA English
DT Article
ID GAS
AB We consider the billiard dynamics in a striplike set that is
tessellated by countably many translated copies Of the same polygon. A
random configuration of semidispersing scatterers is placed in each
copy. The ensemble of dynamical systems thus defined, one for each
global choice of scatterers, is called quenched random Lorentz tube. We
prove that under general conditions, almost every system in the
ensemble is recurrent. (C) 2010 American Institute of Physics.
[doi:10.1063/1.3405290]
C1 [Cristadoro, Giampaolo; Lenci, Marco; Seri, Marcello] Univ Bologna, Dipartimento Matemat, I-40126 Bologna, Italy.
[Seri, Marcello] Univ Erlangen Nurnberg, Dept Math, D-91053 Erlangen, Germany.
RP Cristadoro, G, Univ Bologna, Dipartimento Matemat, Piazza Porta San
Donato 5, I-40126 Bologna, Italy.
EM cristadoro@dm.unibo.it
lenci@dm.unibo.it
seri@dm.unibo.it
CR AARONSON J, 1997, MATH SURVEYS MONOGRA, V50
ALONSO D, 1999, PHYS REV LETT, V82, P1859
ARYA G, 2003, PHYS REV LETT, V91, ARTN 026102
AYYER A, 2009, DISCRETE CONT DYN S, V24, P331, DOI
10.3934/dcds.2009.24.331
CASATI G, 2008, PHYS REV LETT, V101, ARTN 016601
CHERNOV N, 2006, INT C MATH, V2, P1679
CHERNOV N, 2006, MATH SURVEYS MONOGRA, V127
FERES R, 2006, CHEM ENG SCI, V61, P7864, DOI 10.1016/j.ces.2006.08.069
FERES R, 2007, MATH SCI RES I PUBLI, V54, P179
HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298
LENCI M, 2003, ERGOD THEOR DYN SY 3, V23, P869, DOI
10.1017/S0143385702001529
LENCI M, 2006, ERGOD THEOR DYN SY 3, V26, P799, DOI
10.1017/S0143385706000022
LENCI M, 2007, STOCH DYNAM, V7, P53
LENCI M, 2008, J MATH PHYS, V49, ARTN 125213
LI BW, 2005, CHAOS, V15, ARTN 015121
SCHMIDT K, 1998, CR ACAD SCI I-MATH, V327, P837
NR 16
TC 0
PU AMER INST PHYSICS; CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON
QUADRANGLE, STE 1 N O 1,
MELVILLE, NY 11747-4501 USA
SN 1054-1500
DI 10.1063/1.3405290
PD JUN
VL 20
IS 2
AR 023115
SC Mathematics, Applied; Physics, Mathematical
GA 630WB
UT ISI:000280304600015
ER

EF

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