Friday, November 13, 2009

ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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AU Tu, YS
Xiu, P
Wan, RZ
Hu, J
Zhou, RH
Fang, HP
AF Tu, Yusong
Xiu, Peng
Wan, Rongzheng
Hu, Jun
Zhou, Ruhong
Fang, Haiping
TI Water-mediated signal multiplication with Y-shaped carbon nanotubes
SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF
AMERICA
LA English
DT Article
DE confined water; molecular dynamics; molecular signal transmission;
Y-shaped nanochannel; signal transduction
ID MOLECULAR-DYNAMICS; CHANNEL; MECHANISM; TRANSPORT; CONDUCTION;
JUNCTIONS; ELECTRON; LOGIC; FLOW
AB Molecular scale signal conversion and multiplication is of particular
importance in many physical and biological applications, such as
molecular switches, nano-gates, biosensors, and various neural systems.
Unfortunately, little is currently known regarding the signal
processing at the molecular level, partly due to the significant noises
arising from the thermal fluctuations and interferences between branch
signals. Here, we use molecular dynamics simulations to show that a
signal at the single-electron level can be converted and multiplied
into 2 or more signals by water chains confined in a narrow Y-shaped
nanochannel. This remarkable transduction capability of molecular
signal by Y-shaped nanochannel is found to be attributable to the
surprisingly strong dipole-induced ordering of such water chains, such
that the concerted water orientations in the 2 branches of the Y-shaped
nanotubes can be modulated by the water orientation in the main
channel. The response to the switching of the charge signal is very
rapid, from a few nanoseconds to a few hundred nanoseconds.
Furthermore, simulations with various water models, including TIP3P,
TIP4P, and SPC/E, show that the transduction capability of the Y-shaped
carbon nanotubes is very robust at room temperature, with the
interference between branch signals negligible.
C1 [Zhou, Ruhong] IBM Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA.
[Tu, Yusong; Xiu, Peng; Wan, Rongzheng; Hu, Jun; Fang, Haiping] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.
[Tu, Yusong] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China.
[Xiu, Peng] Shandong Univ, Sch Phys, Jinan 250100, Peoples R China.
[Zhou, Ruhong] Columbia Univ, Dept Chem, New York, NY 10027 USA.
RP Zhou, RH, IBM Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA.
EM ruhongz@us.ibm.com
fanghaiping@sinap.ac.cn
CR BACHTOLD A, 2001, SCIENCE, V294, P1317
BALL P, 2008, CHEM REV, V108, P74, DOI 10.1021/cr068037a
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BREWER ML, 2001, BIOPHYS J, V80, P1691
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10.1073/pnas.0604541104
LI WZ, 2001, APPL PHYS LETT, V79, P1879
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XU HQ, 2005, NAT MATER, V4, P649, DOI 10.1038/nmat1471
ZHOU RH, 2004, SCIENCE, V305, P1605
NR 42
TC 0
PU NATL ACAD SCIENCES; 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA
SN 0027-8424
DI 10.1073/pnas.0902676106
PD OCT 27
VL 106
IS 43
BP 18120
EP 18124
SC Multidisciplinary Sciences
GA 512DB
UT ISI:000271222500017
ER

EF

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ISI Web of Knowledge Alert - Majumder M

ISI Web of Knowledge Citation Alert

Cited Article: Majumder M. Nanoscale hydrodynamics - Enhanced flow in carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 1 new records this week (1 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Effects of fluid flow on the oligonucleotide folding in single-walled carbon nanotubes

Authors:
Lim, MCG; Zhong, ZW

Author Full Names:
Lim, M. C. G.; Zhong, Z. W.

Source:
PHYSICAL REVIEW E 80 (4): Art. No. 041915 Part 1 OCT 2009

Language:
English

Document Type:
Article

Author Keywords:
carbon nanotubes; DNA; high-pressure effects; molecular biophysics; molecular dynamics method; nanobiotechnology; van der Waals forces; water

KeyWords Plus:
MOLECULAR-DYNAMICS SIMULATION; SOLID-STATE NANOPORE; DNA TRANSLOCATION; LIQUID WATER; INSERTION; CHANNELS; TRANSPORT; DIAMETER

Abstract:
This paper presents molecular-dynamics (MD) simulations of DNA oligonucleotide and water molecules translocating through carbon nanotube (CNT) channels. An induced pressure difference is applied to the system by pushing a layer of water molecules toward the flow direction to drive the oligonucleotide and other molecules. This MD simulation investigates the changes that occur in the conformation of the oligonucleotide due to water molecules in nanochannels while controlling the temperature and volume of the system in a canonical ensemble. The results show that the oligonucleotide in the (8,8)-(12,12) CNT channel forms a folded state at a lower pressure, whereas the oligonucleotide in the (10,10)-(14,14) CNT channel forms a folded state at a higher pressure instead. The van der Waals forces between the water molecules and the oligonucleotide suggest that the attraction between these two types of molecules results in the linear arrangements of the bases of the oligonucleotide. !
For a larger nanotube channel, the folding of the oligonucleotide is mainly dependent on the solvent (water molecules), whereas pressure, the size of the nanotube junction, and water molecules are the considering factors of the folding of the oligonucleotide at a smaller nanotube channel. For a folded oligonucleotide, the water distribution around the oligonucleotide is concentrated at a smaller range than that for the distribution around an unfolded oligonucleotide.

Reprint Address:
Lim, MCG, Nanyang Technol Univ, Sch Mech & Aerosp Engn, 50 Nanyang Ave, Singapore 639798, Singapore.

Research Institution addresses:
[Lim, M. C. G.; Zhong, Z. W.] Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore

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Cited Reference Count:
42

Times Cited:
0

Publisher:
AMER PHYSICAL SOC; ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA

Subject Category:
Physics, Fluids & Plasmas; Physics, Mathematical

ISSN:
1539-3755

DOI:
10.1103/PhysRevE.80.041915

IDS Number:
513UV

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Friday, October 23, 2009

ISI Web of Knowledge Alert - Hummer, G

ISI Web of Knowledge Citation Alert

Cited Article: Hummer, G. Water conduction through the hydrophobic channel of a carbon nanotube
Alert Expires: 22 OCT 2009
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Ion and Liquid Dependent Dielectric Failure in Electrowetting Systems

Authors:
Raj, B; Dhindsa, M; Smith, NR; Laughlin, R; Heikenfeld, J

Author Full Names:
Raj, Balaji; Dhindsa, Manjeet; Smith, Neil R.; Laughlin, Robert; Heikenfeld, Jason

Source:
LANGMUIR 25 (20): 12387-12392 OCT 20 2009

Language:
English

Document Type:
Article

KeyWords Plus:
SURFACTANTS; VOLTAGE; WATER; CHIP; LENS

Abstract:
Electrowetting devices often utilize aqueous solutions with ionic surfactants and inorganic salts to modify the electrowetting response. It has been observed in low-voltage electrowetting devices (thin dielectric, < 12V) that a frequent onset of dielectric failure (electrolysis) occurs with use of ionic solutes such as potassium chloride (KCl) or sodium dodecyl sulfate. More detailed current-voltage investigations reveal less dielectric failure for the larger size ions. Specifically, improved resistance to failure is seen for surfactant ions carrying it long alkane chain. Therefore, a catanionic surfactant (in Which both ions are amphiphilic) was Custom Synthesized, and elimination of dielectric failure was observed in both negative and positive voltage. Because water is a small molecule that easily penetrates dielectrics, further experiments were performed to show that dielectric failure can also be eliminated by use of larger size polar molecules such as propylene glycol. !
In addition to these results, important parameters Such as conductivity and interfacial tensions are reported.

Reprint Address:
Heikenfeld, J, Univ Cincinnati, Novel Devices Lab, Dept Elect & Comp Engn, Cincinnati, OH 45221 USA.

Research Institution addresses:
[Raj, Balaji; Dhindsa, Manjeet; Smith, Neil R.; Laughlin, Robert; Heikenfeld, Jason] Univ Cincinnati, Novel Devices Lab, Dept Elect & Comp Engn, Cincinnati, OH 45221 USA

E-mail Address:
heikenjc@ucmail.uc.edu

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Cited Reference Count:
24

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary

ISSN:
0743-7463

DOI:
10.1021/la9016933

IDS Number:
504DO

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Title:
Effect of Temperature on the Structure and Phase Behavior of Water Confined by Hydrophobic, Hydrophilic, and Heterogeneous Surfaces

Authors:
Giovambattista, N; Rossky, PJ; Debenedetti, PG

Author Full Names:
Giovambattista, Nicolas; Rossky, Peter J.; Debenedetti, Pablo G.

Source:
JOURNAL OF PHYSICAL CHEMISTRY B 113 (42): 13723-13734 OCT 22 2009

Language:
English

Document Type:
Article

KeyWords Plus:
MOLECULAR-DYNAMICS SIMULATIONS; THERMAL-EXPANSION; LIQUID WATER; NANOSCALE CONFINEMENT; REVERSE MICELLES; AQUEOUS-SOLUTION; EWALD SUMMATION; LENGTH SCALES; HYDRATION; PRESSURE

Abstract:
We perform molecular dynamics simulations of water confined between atomically detailed hydrophobic, hydrophilic and heterogeneous (patchy) nanoscale plates. We study the effects of temperature 220 <= T <= 300 K on confined water's behavior at various pressures -0.2 <= P <= 0.2 GPa and plate separations 0.5 <= d <= 1.6 nm. Combining this with our earlier results on the same system [Giovambattista, N.; Rossky, P. J.; Debenedetti, P. G. Phys, Rev. E: Stat., Nordinear, Soft Matter Phys. 2006, 73, 041604; Giovambattista, N.; Rossky, P. J.; Debenedetti, P. G. J. Phys. Chem. C, 2007,11, 1323], where pressure was varied at constant temperature, allows us to compare water's behavior in nanoscale confinement, upon isobaric cooling and isothermal compression, corresponding to paths of interest in protein denaturation. At a fixed temperature, water confined between hydrophobic plates can form vapor, liquid, or crystal (bilayer ice) phases. depending on the values of P and d. The P-d ph!
ase diagrams at T = 300 K and T = 220 K show that cooling, suppresses the vapor phase and stabilizes the liquid and crystal phases. The critical separation d(e)(P), below which vapor forms, shifts to lower values of d and P upon cooling. The density profiles show that, upon cooling, water approaches the hydrophobic plates. Hence, the effective hydrophobicity of the plate decreases as T decreases, consistent with the suppression of the vapor phase upon cooling, However. both the orientation of water's molecules at the interface and the water contact angle on the hydrophobic Surface show practically no temperature dependence. Simulations of water confined by heterogeneous plates decorated with hydrophobic and hydrophilic patches reveal that cooling leads to appreciable blurring of the differences between water densities at hydrophobic and hydrophilic, surfaces. This observation, together with remarkable similarities in confined water's response to isobaric cooling and to isot!
hermal compression, suggests that (fie invasion of hydrophobic!
cavitie
s by water is all important mechanism underlying both pressure and cold denaturation of proteins,

Reprint Address:
Debenedetti, PG, Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA.

Research Institution addresses:
[Giovambattista, Nicolas; Debenedetti, Pablo G.] Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA; [Giovambattista, Nicolas] CUNY Brooklyn Coll, Dept Phys, Brooklyn, NY 11210 USA; [Rossky, Peter J.] Univ Texas Austin, Dept Chem & Biochem, Inst Computat Engn & Sci, Austin, TX 78712 USA

E-mail Address:
pdebene@princeton.edu

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Cited Reference Count:
79

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Physical

ISSN:
1520-6106

DOI:
10.1021/jp9018266

IDS Number:
505EB

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