Friday, October 24, 2008

ISI Web of Knowledge Alert - Hummer, G

ISI Web of Knowledge Citation Alert (Solaris 2.1)

Cited Article: Hummer, G. Water conduction through the hydrophobic channel of a carbon nanotube
Alert Expires: 22 OCT 2009
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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Title:
Water in single-walled aluminosilicate nanotubes: Diffusion and adsorption properties

Authors:
Konduri, S; Tong, HM; Chempath, S; Nair, S

Author Full Names:
Konduri, Suchitra; Tong, Ho Ming

Source:
JOURNAL OF PHYSICAL CHEMISTRY C 112 (39): 15367-15374 OCT 2 2008

Language:
English

Document Type:
Article

Keywords Plus:
MIXED-OXIDE NANOTUBES; CARBON NANOTUBES; MOLECULAR-DYNAMICS; TRANSPORT; MEMBRANES; ZEOLITES; SIMULATIONS; RESISTANCES; DIMENSIONS; SILICALITE

Abstract:
Single-walled aluminosilicate nanotubes are attractive materials for construction of nanofluidic devices. They have a well-defined structure, a hydrophilic interior with periodic wide and narrow regions, precisely tunable length and diameter, and a functionalizable interior for tuning mass transport and adsorption properties. We report a computational and experimental investigation that highlights the unique adsorption and diffusive water transport properties of these nanotubes. Axial self-diffusivities of water molecules (at loadings ranging from near-infinite dilution to near-saturation) are calculated by molecular dynamics (MD) simulations, whereas adsorption properties are computed with grand canonical Monte Carlo (GCMC) simulations and are also compared to experimental data. The transport diffusivities are evaluated through the Darken approximation. Water transport in these nanotubes at room temperature was observed to occur via Fickian diffusion. The self-diffusivity d!
ecreases with an increase in water content,. whereas the transport diffusivity exhibited a maximum at intermediate water content. The diffusivities were comparable to the diffusivity of bulk liquid water and hence are considerably higher than in other nanoporous aluminosilicates such as zeolites. The computed adsorption isotherms exhibited inflections at low partial pressures (similar to 6 mm Hg) with a large fraction of adsorption occurring in the pores of the nanotube displaying remarkable hydrophilicity. As a combined result of the relatively fast Fickian diffusion of water, hydrophilicity of the nanotubes, and short nanotube lengths, the diffusive water flux through an aluminosilicate nanotube film is predicted to be quite high (10(2)-10(3) mol m(-2) s(-1)), even at very low pressure differentials across the membrane.

Reprint Address:
Nair, S, Georgia Inst Technol, Sch Chem & Biomol Engn, 311 Ferst Dr NW, Atlanta, GA 30332 USA.

Research Institution addresses:
Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA; Los Alamos Natl Lab, Theoret Chem & Mol Phys Grp, Los Alamos, NM 87545 USA

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Cited Reference Count:
38

Times Cited:
0

Publisher:
AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Subject Category:
Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary

ISSN:
1932-7447

DOI:
10.1021/jp8025144

IDS Number:
353FT

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Title:
Bacterial mechanosensitive channels: Experiment and theory

Authors:
Corry, B; Martinac, B

Author Full Names:
Corry, Ben; Martinac, Boris

Source:
BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES 1778 (9): 1859-1870 SEP 2008

Language:
English

Document Type:
Review

Author Keywords:
MS channels; patch clamp; bilayer model; mechanosensory transduction; EPR spectroscopy; FRET; molecular dynamics; Brownian dynamics

Keywords Plus:
MOLECULAR-DYNAMICS SIMULATIONS; SMALL-CONDUCTANCE MSCS; ESCHERICHIA-COLI MSCS; ION-CHANNEL; GATING MECHANISM; PATCH-CLAMP; FUNCTIONAL RECONSTITUTION; BROWNIAN DYNAMICS; MYCOBACTERIUM-TUBERCULOSIS; ACETYLCHOLINE-RECEPTOR

Abstract:
Since their discovery in Escherichia coli some 20 years ago, studies of bacterial mechanosensitive (MS) ion channels have been at the forefront of the MS channel research field. Two major events greatly advanced the research on bacterial MS channels: (i) cloning of MscL and MscS, the MS channels of Large and Small conductance, and (ii) solving their 3D crystal structure. These events enabled further experimental studies employing EPR and FRET spectroscopy in addition to patch clamp and molecular biological techniques that have successfully been used in characterization of the structure and function of bacterial NIS channels. In parallel with the experimental studies computational modelling has been applied to elucidate the molecular dynamics of MscL and MscS, which has significantly contributed to our understanding of basic physical principles of the mechanosensory transduction in living organisms. (C) 2007 Elsevier B.V. All rights reserved.

Reprint Address:
Martinac, B, Univ Queensland, Sch Biomed Sci, Brisbane, Qld 4072, Australia.

Research Institution addresses:
Univ Queensland, Sch Biomed Sci, Brisbane, Qld 4072, Australia; Univ Western Australia, Sch Biomed Biomol & Chem Sci, Crawley, WA 6008, Australia

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Cited Reference Count:
101

Times Cited:
0

Publisher:
ELSEVIER SCIENCE BV; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS

Subject Category:
Biochemistry & Molecular Biology; Biophysics

ISSN:
0005-2736

DOI:
10.1016/j.bbamem.2007.06.022

IDS Number:
357WF

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