Cited Article:    Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
 Alert Expires:    18 OCT 2009
 Number of Citing Articles:    1 new records this week (1 in this e-mail)
 Organization ID:  3b97d1bbc1878baed0ab183d8b03130b
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AU Koshino, M
   Solin, N
   Tanaka, T
   Isobe, H
   Nakamura, E
AF Koshino, Masanori
   Solin, Niclas
TI Imaging the passage of a single hydrocarbon chain through a nanopore
SO NATURE NANOTECHNOLOGY
LA English
DT Article
ID CARBON NANOTUBES; MOLECULES; MEMBRANE; SURFACE; MOTION; C-60
AB Molecular transport through nanoscale pores in films, membranes and
   wall structures is of fundamental importance in a number of physical,
   chemical and biological processes(1-6). However, there is a lack of
   experimental methods that can obtain information on the structure and
   orientation of the molecules as they pass through the pore, and their
   interactions with the pore during passage. Imaging with a transmission
   electron microscope is a powerful method for studying structural
   changes in single molecules as they move(7,8) and for imaging molecules
   confined inside carbon nanotubes(9). Here, we report that such imaging
   can be used to observe the structure and orientation of a hydrocarbon
   chain as it passes through nanoscale defects in the walls of a
   single-walled carbon nanotube to the vacuum outside, and also to study
   the interactions between the chain and the nanopore. Based on
   experiments at 293 K and 4 K we conclude that the major energy source
   for the molecular motions observed at 4 K is the electron beam used for
   the imaging.
C1 Japan Sci & Technol Agcy JST, Nakamura Funct Carbon Cluster Project, Exploratory Res Adv Technol ERATO, Bunkyo Ku, Tokyo 1130033, Japan.
   Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan.
RP Isobe, H, Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691
   Stockholm, Sweden.
CR BANDOSZ TJ, 2003, CHEM PHYS CARBON, V28, P41
   BORGNIA M, 1999, ANNU REV BIOCHEM, V68, P425
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   HASHIMOTO A, 2004, P NATL ACAD SCI USA, V101, P8527, DOI
   10.1073/pnas.0400596101
   HIRSCH A, 1992, ANGEW CHEM INT EDIT, V31, P766
   HOLT JK, 2006, SCIENCE, V312, P1034, DOI 10.1126/science.1126298
   ISOBE H, 2007, P NATL ACAD SCI USA, V104, P14895, DOI
   10.1073/pnas.0705010104
   KASIANOWICZ JJ, 1996, P NATL ACAD SCI USA, V93, P13770
   KOSHINO M, 2007, SCIENCE, V316, P853
   LIU Z, 2007, J AM CHEM SOC, V129, P6666, DOI 10.1021/ja068516r
   LIU Z, 2007, NAT NANOTECHNOL, V2, P422, DOI 10.1038/nnqno.2007.187
   MEYER JC, 2008, NANO LETT, DOI 10.1021/NL801386M
   MULDER M, 1991, BASIC PRINCIPLES MEM
   NAKAMURA E, 2008, J AM CHEM SOC, V130, P7808, DOI 10.1021/ja8022708
   NISHIO M, 1995, TETRAHEDRON, V51, P8665
   RAO MB, 1993, J MEMBRANE SCI, V85, P253
   SOLIN N, 2007, CHEM LETT, V36, P1208, DOI 10.1246/cl.2007.1208
   SUENAGA K, 2007, NAT NANOTECHNOL, V2, P358, DOI 10.1038/nnano.2007.141
NR 18
TC 0
PU NATURE PUBLISHING GROUP; MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1
   9XW, ENGLAND
SN 1748-3387
DI 10.1038/nnano.2008.263
PD OCT
PY 2008
VL 3
IS 10
BP 595
EP 597
SC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary
GA 364CR
UT ISI:000260314300010
ER
EF
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