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Title: Drainage of a Wetting Liquid: Effective Slippage or Polymer Depletion? |
Authors: |
Author Full Names: Cayer-Barrioz, J.; Mazuyer, D.; Tonck, A.; Yamaguchi, E. |
Source: TRIBOLOGY LETTERS 32 (2): 81-90 NOV 2008 |
Language: English |
Document Type: Article |
Author Keywords: Friction; Slip; Surface force apparatus |
Keywords Plus: FLUID-SOLID INTERFACE; HYDROPHOBIC SURFACES; BOUNDARY-CONDITION; HYDRODYNAMIC SLIP; SOLVATION FORCES; NO-SLIP; FILMS; ADSORPTION; FRICTION; LAYERS |
Abstract: A surface force apparatus has been used to investigate the drainage of a viscosity improver lubricant. The characterization of the VI confined interface has been performed. Surprisingly, dynamical measurements enlighten a significant negative value of the immobile layer thickness. This result is discussed in terms of occurrence of slip at the wall, liquid-solid interface wettability, surface roughness and cleanliness, and friction experiments. Consequently, an interface molecular organization modelling is proposed based on polymer depletion near the solid-liquid interface. |
Reprint Address: Cayer-Barrioz, J, Ecole Cent Lyon, LTDS, UMR5513, CNRS, 36 Ave Guy Collongue, F-69134 Ecully, France. |
Research Institution addresses: [Cayer-Barrioz, J.; Mazuyer, D.; Tonck, A.] Ecole Cent Lyon, LTDS, UMR5513, CNRS, F-69134 Ecully, France; [Yamaguchi, E.] Chevron Oronite Co LLC, Richmond, CA 94802 USA |
E-mail Address: juliette.cayer-barrioz@ec-lyon.fr |
Cited References: BARRAT JL, 1999, PHYS REV LETT, V82, P4671. BAUDRY J, 2001, LANGMUIR, V17, P5232. BONACCURSO E, 2002, PHYS REV LETT, V88, ARTN 076103. BONACCURSO E, 2003, PHYS REV LETT, V90, ARTN 144501. CARAMBASSIS A, 1998, PHYS REV LETT, V80, P5357. COTTINBIZONNE C, 2005, PHYS REV LETT, V94, ARTN 056102. DEGENNES PG, 1979, SCALING CONCEPTS POL. DEGENNES PG, 1981, MACROMOLECULES, V14, P1637. DEGENNES PG, 1987, ADV COLLOID INTERFAC, V27, P189. DEGENNES PG, 2002, LANGMUIR, V18, P3413. DERJAGUIN BV, 1987, LANGMUIR, V3, P607. DONATH E, 1996, LANGMUIR, V12, P3425. GALEA TM, 2004, LANGMUIR, V20, P3477, DOI 10.1021/la035880k. GAO JP, 1997, J CHEM PHYS, V106, P4309. GAO JP, 2000, TRIBOL LETT, V9, P3. GEORGES JM, 1993, J CHEM PHYS, V98, P7345. GRANICK S, 2003, NAT MATER, V2, P221. HEINBUCH U, 1989, PHYS REV A, V40, P1144. HENRY CL, 2004, PHYSICA A, V339, P60, DOI 10.1016/j.physa.2004.03.044. HORN RG, 2000, J CHEM PHYS, V112, P6424. INN YW, 1996, PHYS REV LETT, V76, P467. KUHL TL, 1998, MACROMOLECULES, V31, P8250. LARSON RG, 1999, STRUCTURE RHEOLOGY C. LEGER L, 1997, J PHYS-CONDENS MAT, V9, P7719. MANIAS E, 1996, LANGMUIR, V12, P4587. MARK JE, 1996, PHYS PROPERTIES POLY. MAZUYER D, 2007, SUPERLUBRICITY, P397. MCGUIGGAN PM, 2007, MACROMOLECULES, V40, P2126, DOI 10.1021/ma061750h. NETO C, 2005, REP PROG PHYS, V68, P2859, DOI 10.1088/0034-4885/68/12/R05. PIT R, 1999, TRIBOL LETT, V7, P147. PIT R, 2000, PHYS REV LETT, V85, P980. SANCHEZREYES J, 2003, LANGMUIR, V19, P3304, DOI 10.1021/la0265326. SPIKES H, 2003, LANGMUIR, V19, P5065, DOI 10.1021/la034123j. SPIKES HA, 2003, THINNING FILMS TRIBO, P525. STEINBERGER A, 2007, NAT MATER, V6, P665, DOI 10.1038/nmat1962. SUN GX, 2002, J CHEM PHYS, V117, P10311, DOI 10.1063/1.1515970. THOMPSON PA, 1997, NATURE, V389, P360. TONCK A, 1989, THESIS ECOLE CENTR L. TONCK A, 1999, P I MECH ENG J-J ENG, V213, P353. TUINIER R, 2005, J PHYS CONDENS MATT, V17, L4. VINOGRADOVA OI, 1999, INT J MINER PROCESS, V56, P31. WENZEL RN, 1936, IND ENG CHEM, V28, P988. ZHU YX, 2002, PHYS REV LETT, V88, P6102. |
Cited Reference Count: 43 |
Times Cited: 0 |
Publisher: SPRINGER/PLENUM PUBLISHERS; 233 SPRING ST, NEW YORK, NY 10013 USA |
Subject Category: Engineering, Chemical; Engineering, Mechanical |
ISSN: 1023-8883 |
DOI: 10.1007/s11249-008-9365-7 |
IDS Number: 369MY |
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Title: Squeeze Film Lubrication in Silicone Oil: Experimental Test of the No-Slip Boundary Condition at Solid-Liquid Interfaces |
Authors: |
Author Full Names: Honig, Christopher D. F.; Ducker, William A. |
Source: JOURNAL OF PHYSICAL CHEMISTRY C 112 (44): 17324-17330 NOV 6 2008 |
Language: English |
Document Type: Article |
Keywords Plus: ATOMIC-FORCE MICROSCOPE; SURFACE FORCES; NEWTONIAN LIQUIDS; NONPOLAR MEDIA; PLANE SURFACE; VISCOUS FLUID; SLOW MOTION; THIN-FILMS; WATER; CANTILEVERS |
Abstract: The hydrodynamic force between a spherical glass particle (radius similar to 10 mu m) and a smooth, flat glass plate in Newtonian silicone oil (viscosity, eta similar to 95 mPa s) was measured using the atomic force microscopy (AFM) colloidal probe technique and was compared to Reynolds lubrication theory. When the particle and plate were coated with a hydrophobic silane, the measured forces were consistent with Reynolds lubrication theory without the need to introduce the concept of a slip length. When the particle was hydrophilic, the results were more variable, sometimes being consistent with the no-slip boundary condition and sometimes being better fitted by invoking a constant slip length (up to 33 nm). The hydrophilic system was not well characterized because the hydrophilic solid may have entrained or attracted a layer of water (eta = 0.001 Pa s) of unknown thickness, which would lubricate the flow and explain the apparent slip length. In addition, all AFM force measu! rements suffer from the problem that the solids occasionally have rough patches, steps, or attached nanoparticles, which will affect the force and may cause departure from a theory that does not account for their presence. We conclude that the no-slip boundary condition is valid for solid-liquid interfaces but that some experiments entail conditions, for example, surface roughness or lubricating layers, that may give the appearance of violating the no-slip boundary condition. |
Reprint Address: Ducker, WA, Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia. |
Research Institution addresses: [Honig, Christopher D. F.; Ducker, William A.] Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia; [Honig, Christopher D. F.; Ducker, William A.] Univ Melbourne, Particulate Fluids Proc Ctr, Melbourne, Vic 3010, Australia; [Ducker, William A.] Virginia Tech, Dept Chem Engn, Blacksburg, VA 24061 USA |
E-mail Address: wducker@vt.edu |
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Cited Reference Count: 38 |
Times Cited: 0 |
Publisher: AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
Subject Category: Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary |
ISSN: 1932-7447 |
DOI: 10.1021/jp804736a |
IDS Number: 367DR |
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