Friday, January 15, 2010

ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 09 NOV 2010
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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PT J
*Record 1 of 2.
L5 <http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS&DestLinkType=FullRecord;UT=000260469400003>
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AU Wiggins, P
AF Wiggins, Philippa
TI Life Depends upon Two Kinds of Water
SO PLOS ONE
LA English
DT Article
AB Background. Many well-documented biochemical processes lack a molecular
mechanism. Examples are: how ATP hydrolysis and an enzyme contrive to
perform work, such as active transport; how peptides are formed from
amino acids and DNA from nucleotides; how proteases cleave peptide
bonds, how bone mineralises; how enzymes distinguish between sodium and
potassium; how chirality of biopolymers was established prebiotically.
Methodology/Principal Findings. It is shown that involvement of water
in all these processes is mandatory, but the water must be of the
simplified configuration in which there are only two strengths of
water-water hydrogen bonds, and in which these two types of water
coexist as microdomains throughout the liquid temperature range. Since
they have different strengths of hydrogen bonds, the microdomains
differ in all their physical and chemical properties. Solutes partition
asymmetrically, generating osmotic pressure gradients which must be
compensated for or abolished. Displacement of the equilibrium between
high and low density waters incurs a thermodynamic cost which limits
solubility, depresses ionisation of water, drives protein folding and
prevents high density water from boiling at its intrinsic boiling point
which appears to be below 0 degrees C. Active processes in biochemistry
take place in sequential partial reactions, most of which release small
amounts of free energy as heat. This ensures that the system is never
far from equilibrium so that efficiency is extremely high. Energy
transduction is neither possible and nor necessary. Chirality was
probably established in prebiotic clays which must have carried stable
populations of high density and low density water domains. Bioactive
enantiomorphs partition into low density water in which they polymerise
spontaneously. Conclusions/Significance. The simplified model of water
has great explanatory power.
RP Wiggins, P, Mairangi Bay, Auckland, New Zealand.
EM p.wiggins@paradise.net.nz
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NR 38
TC 0
PU PUBLIC LIBRARY SCIENCE; 185 BERRY ST, STE 1300, SAN FRANCISCO, CA 94107
USA
SN 1932-6203
DI 10.1371/journal.pone.0001406
PD JAN 9
VL 3
IS 1
AR e1406
GA 366GT
UT ISI:000260469400003
ER

PT J
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AU Baumgaertner, A
AF Baumgaertner, A.
TI Fast-ion transport in peptide nanochannels
SO MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE
MATERIALS
LA English
DT Proceedings Paper
DE Ion conduction; Rectification; Molecular dynamics simulation;
Incommensurability; Ratchet; Potassium channel
ID CARBON NANOTUBE MEMBRANES; K+ SELECTIVITY FILTER; SUPERIONIC
CONDUCTORS; MASS-TRANSPORT; CHANNEL; HOLLANDITE; DYNAMICS; MODELS; ORDER
AB This review summarizes recent results of the ion transport in narrow
peptide nanochannels (PNCs) conducting ions and water molecules at
various densities. The molecular structure of the nanochannel is a
periodic continuation of the short selectivity pore of a biological
potassium channel. The ion conductivity of a PNC can reach ion
velocities up to 50 m/s. This phenomena is based on a fine tuned
interplay between the three constituents of the PNC: the ions, the
water molecules, and the flexible carbonyl groups of the channel's
backbone, which represents a one-dimensional fluctuating lattice
potential for ions and water. The Unidirectional transport is based on
hopping processes of bound ion-water pairs ('permons') mediated by the
lattice potential. (c) 2009 Elsevier B.V. All rights reserved.
C1 Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany.
RP Baumgaertner, A, Forschungszentrum Julich, Inst Festkorperforsch,
D-52425 Julich, Germany.
EM a.baumgaertner@fz-juelich.de
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NR 45
TC 0
PU ELSEVIER SCIENCE BV; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
SN 0921-5107
DI 10.1016/j.mseb.2009.04.021
PD DEC 15
VL 165
IS 3
SI Sp. Iss. SI
BP 261
EP 265
SC Materials Science, Multidisciplinary; Physics, Condensed Matter
GA 538BA
UT ISI:000273157800029
ER

EF

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