Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
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AU Wu, J
Paudel, KS
Strasinger, C
Hammell, D
Stinchcomb, AL
Hinds, BJ
AF Wu, Ji
Paudel, Kalpana S.
Strasinger, Caroline
Hammell, Dana
Stinchcomb, Audra L.
Hinds, Bruce J.
TI Programmable transdermal drug delivery of nicotine using carbon
nanotube membranes
SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF
AMERICA
LA English
DT Article
DE electroosmosis; electrophoresis; smoking cessation; medical device
ID HAIRLESS GUINEA-PIGS; ELECTROOSMOTIC FLOW; MASS-TRANSPORT; SKIN; MODEL;
PHARMACOKINETICS; IONTOPHORESIS; NALTREXONE; ELECTRODE; PRODRUGS
AB Carbon nanotube (CNT) membranes were employed as the active element of
a switchable transdermal drug delivery device that can facilitate more
effective treatments of drug abuse and addiction. Due to the
dramatically fast flow through CNT cores, high charge density, and
small pore dimensions, highly efficient electrophoretic pumping through
functionalized CNT membrane was achieved. These membranes were
integrated with a nicotine formulation to obtain switchable transdermal
nicotine delivery rates on human skin (in vitro) and are consistent
with a Fickian diffusion in series model. The transdermal nicotine
delivery device was able to successfully switch between high (1.3 +/-
0.65 mu mol/hr-cm(2)) and low (0.33 +/- 0.22 mu mol/hr-cm(2)) fluxes
that coincide with therapeutic demand levels for nicotine cessation
treatment. These highly energy efficient programmable devices with
minimal skin irritation and no skin barrier disruption would open an
avenue for single application long-wear patches for therapies that
require variable or programmable delivery rates.
C1 [Paudel, Kalpana S.; Strasinger, Caroline; Hammell, Dana; Stinchcomb, Audra L.] Univ Kentucky, Coll Pharm, Lexington, KY 40536 USA.
[Wu, Ji; Hinds, Bruce J.] Univ Kentucky, Dept Chem & Mat Engn, Lexington, KY 40506 USA.
RP Stinchcomb, AL, Univ Kentucky, Coll Pharm, Lexington, KY 40536 USA.
EM audra.stinchcomb@uky.edu
bjhinds@engr.uky.edu
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NR 30
TC 0
PU NATL ACAD SCIENCES; 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA
SN 0027-8424
DI 10.1073/pnas.1004714107
PD JUN 29
VL 107
IS 26
BP 11698
EP 11702
SC Multidisciplinary Sciences
GA 618DT
UT ISI:000279332300011
ER
PT J
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AU Yu, HQ
Li, YF
Li, H
Zhang, K
An, CG
Liu, XF
Liew, KM
AF Yu, H. Q.
Li, Y. F.
Li, H.
Zhang, K.
An, C. G.
Liu, X. F.
Liew, K. M.
TI Methane Molecules Drive Water Molecules along Diameter-Gradient SWCNTs
with Junctions
SO JOURNAL OF PHYSICAL CHEMISTRY B
LA English
DT Article
ID WALLED CARBON NANOTUBES; TRANSPORT; MODEL; FLOW
AB We report the transport behavior of water molecules along a system of
coaxial single-walled carbon nanotubes (SWCNTs) of different diameters
with junctions under the driving force of methane molecules. The
junctions are potential barriers to the transport of water molecules
through SWCNTs. However, methane molecules can overcome these potential
barriers and pull the water molecules across the junction region from
one compartment to the next. Although a junction is an obstacle to
water transport through SWCNTs, the presence of more junctions gives
methane molecules a longer lasting driving force that helps them to
pull the water molecules out of the SWCNTs.
C1 [Yu, H. Q.; Li, Y. F.; Li, H.; Zhang, K.; An, C. G.; Liu, X. F.] Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Peoples R China.
[Liew, K. M.] City Univ Hong Kong, Dept Bldg & Construct, Kowloon, Hong Kong, Peoples R China.
RP Li, H, Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut &
Proc Mat, Jinan 250061, Peoples R China.
EM lihuilmy@hotmail.com
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NR 25
TC 0
PU AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
SN 1520-6106
DI 10.1021/jp102810j
PD JUL 8
VL 114
IS 26
BP 8676
EP 8679
SC Chemistry, Physical
GA 617LP
UT ISI:000279282600012
ER
PT J
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AU Lopez-Lorente, AI
Simonet, BM
Valcarcel, M
AF Lopez-Lorente, A. I.
Simonet, B. M.
Valcarcel, M.
TI The Potential of Carbon Nanotube Membranes for Analytical Separations
SO ANALYTICAL CHEMISTRY
LA English
DT Article
ID FAST MASS-TRANSPORT; ELECTROOSMOTIC FLOW; WATER; FABRICATION;
BUCKYPAPERS; FILMS; TRANSPARENT; MODULATION; FILTERS; ARRAYS
AB Advances in nanotechnology have enabled the development of nanoporous
membranes based on carbon nanotubes, which, by virtue of their
exceptional properties, constitute excellent supports for analytical
processes, including the selective separation of some molecules.
C1 [Valcarcel, M.] Univ Cordoba, Dept Analyt Chem, E-14071 Cordoba, Spain.
RP Valcarcel, M, Univ Cordoba, Dept Analyt Chem, E-14071 Cordoba, Spain.
EM qa1meobj@uco.es
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NR 59
TC 0
PU AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
SN 0003-2700
DI 10.1021/ac902629n
PD JUL 1
VL 82
IS 13
BP 5399
EP 5407
SC Chemistry, Analytical
GA 617AO
UT ISI:000279253300003
ER
EF
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