Cited Article: Hummer, G. Water conduction through the hydrophobic channel of a carbon nanotube
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Title:
Electrokinetic properties of monovalent electrolytes confined in charged nanopores: Effect of geometry and ionic short-range correlations
Authors:
Sanchez-Arellano, E; Olivares, W; Lozada-Cassou, M; Jimenez-Angeles, F
Author Full Names:
Sanchez-Arellano, Enrique; Olivares, Wilmer; Lozada-Cassou, Marcelo; Jimenez-Angeles, Felipe
Source:
JOURNAL OF COLLOID AND INTERFACE SCIENCE 330 (2): 474-482 FEB 15 2009
Language:
English
Document Type:
Article
Author Keywords:
Electrokinetic properties; Cylindrical nanopore; Slitlike nanopore; Capillary conductance; Electroviscosity; Streaming potential
KeyWords Plus:
ELECTRICAL DOUBLE-LAYER; FINE CYLINDRICAL CAPILLARIES; HYPERNETTED-CHAIN; MONTE-CARLO; POROUS-MEDIA; FLOW; POTENTIALS; MICROPORES; SIMULATION; ISOTHERMS
Abstract:
The electrokinetic properties (such as capillary conductance, electroviscosity, and the streaming potential) are obtained for a restricted primitive model electrolyte confined in a slitlike nanopore made up of two infinite parallel plates and in a cylindrical cavity of infinite extension. The hypernetted chain/mean spherical approximation (HNC/MSA) is used to obtain the equilibrium ionic concentration profiles inside the pores, which in turn are used to Calculate the electrokinetic properties via linear hydrodynamic equations. Our results are compared with those obtained via the classical Poisson-Boltzmann (PB) theory. Important quantitative and qualitative effects, attributed to geometry and to the proper consideration of short-range correlations by HNC/MSA, are discussed. (C) 2008 Elsevier Inc. All rights reserved.
Reprint Address:
Jimenez-Angeles, F, Inst Mexicano Petr, Programa Ingn Mol, Lazaro Cardenas 152, Mexico City 07730, DF, Mexico.
Research Institution addresses:
[Lozada-Cassou, Marcelo; Jimenez-Angeles, Felipe] Inst Mexicano Petr, Programa Ingn Mol, Mexico City 07730, DF, Mexico; [Sanchez-Arellano, Enrique] Univ Autonoma Metropolitana Iztapalapa, Dept Fis, Mexico City 09340, DF, Mexico; [Sanchez-Arellano, Enrique] Univ Autonoma Ciudad Mexico, Colegio Ciencia & Tecnol, Mexico City 09620, DF, Mexico; [Olivares, Wilmer] Univ Los Andes, Fac Ciencias, Dept Quim, Grp Quim Teor, Merida 5101, Venezuela
E-mail Address:
fangeles@imp.mx
Cited References:
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Cited Reference Count:
36
Times Cited:
0
Publisher:
ACADEMIC PRESS INC ELSEVIER SCIENCE; 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA
Subject Category:
Chemistry, Physical
ISSN:
0021-9797
DOI:
10.1016/j.jcis.2008.10.051
IDS Number:
398VW
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