Thursday, July 2, 2009

ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 18 OCT 2009
Number of Citing Articles: 3 new records this week (3 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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*Record 1 of 3.
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AU Srikar, R
Yarin, AL
Megaridis, CM
AF Srikar, R.
Yarin, A. L.
Megaridis, C. M.
TI Fluidic delivery of homogeneous solutions through carbon tube bundles
SO NANOTECHNOLOGY
LA English
DT Article
ID POLYMER NANOFIBERS; RHODAMINE-B; NANOTUBES; TRANSPORT; RELEASE;
MEMBRANES; DEVICES; FLOW
AB A wide array of technological applications requires localized high-rate
delivery of dissolved compounds (in particular, biological ones), which
can be achieved by forcing the solutions or suspensions of such
compounds through nano or microtubes and their bundled assemblies.
Using a water-soluble compound, the fluorescent dye Rhodamine 610
chloride, frequently used as a model drug release compound, it is shown
that deposit buildup on the inner walls of the delivery channels and
its adverse consequences pose a severe challenge to implementing
pressure-driven long-term fluidic delivery through nano and
microcapillaries, even in the case of such homogeneous solutions.
Pressure-driven delivery (3-6 bar) of homogeneous dye solutions through
macroscopically-long (similar to 1 cm) carbon nano and microtubes with
inner diameters in the range 100 nm-1 mu m and their bundled parallel
assemblies is studied experimentally and theoretically. It is shown
that the flow delivery gradually shifts from fast convection-dominated
(unobstructed) to slow jammed convection, and ultimately to
diffusion-limited transport through a porous deposit. The
jamming/clogging phenomena appear to be rather generic: they were
observed in a wide concentration range for two fluorescent dyes in
carbon nano and microtubes, as well as in comparable transparent glass
microcapillaries. The aim of the present work is to study the physics
of jamming, rather than the chemical reasons for the affinity of dye
molecules to the tube walls.
C1 [Srikar, R.; Yarin, A. L.; Megaridis, C. M.] Univ Illinois, Dept Mech & Ind Engn, Chicago, IL 60607 USA.
[Yarin, A. L.] Tech Univ Darmstadt, Ctr Smart Interfaces, D-64287 Darmstadt, Germany.
RP Yarin, AL, Univ Illinois, Dept Mech & Ind Engn, Chicago, IL 60607 USA.
EM ayarin@uic.edu
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NR 28
TC 0
PU IOP PUBLISHING LTD; DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND
SN 0957-4484
DI 10.1088/0957-4484/20/27/275706
PD JUL 8
VL 20
IS 27
AR 275706
SC Engineering, Multidisciplinary; Nanoscience & Nanotechnology; Materials
Science, Multidisciplinary; Physics, Applied
GA 459GN
UT ISI:000267089600028
ER

PT J
*Record 2 of 3.
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AU Liang, CD
Xie, H
Schwartz, V
Howe, J
Dai, S
Overbury, SH
AF Liang, Chengdu
Xie, Hong
Schwartz, Viviane
Howe, Jane
Dai, Sheng
Overbury, Steven H.
TI Open-Cage Fullerene-like Graphitic Carbons as Catalysts for Oxidative
Dehydrogenation of Isobutane
SO JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
LA English
DT Article
ID ORDERED MESOPOROUS POLYMERS; BLOCK-COPOLYMERS; NANOTUBES; ETHYLBENZENE;
TRANSFORMATION; FRAMEWORKS
AB We report herein a facile synthesis of fullerene-like cages, which can
be opened and closed through simple thermal treatments. A glassy carbon
with enclosed fullerene-like cages of 2-3 nm was synthesized through a
soft-template approach that created open mesopores of 7 nm. The open
mesopores provided access to the fullerene-like cages, which were
opened and closed through heat treatments in air and inert gas at
various temperatures. Catalytic measurements showed that the open cages
displayed strikingly higher activity for the oxidative dehydrogenation
of isobutane in comparison to the closed ones. We anticipate that this
synthesis approach could unravel an avenue for pursuing fundamental
understanding of the unique catalytic properties of graphitic carbon
nanostructures.
C1 [Liang, Chengdu; Xie, Hong; Schwartz, Viviane; Dai, Sheng; Overbury, Steven H.] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA.
[Howe, Jane] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA.
[Dai, Sheng; Overbury, Steven H.] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA.
RP Liang, CD, Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN
37831 USA.
EM liangcn@ornl.gov
schwartzv@ornl.gov
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NR 30
TC 0
PU AMER CHEMICAL SOC; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
SN 0002-7863
DI 10.1021/ja900888p
PD JUN 10
VL 131
IS 22
BP 7735
EP 7741
SC Chemistry, Multidisciplinary
GA 460HD
UT ISI:000267177900063
ER

PT J
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AU Tang, CY
Zhang, Q
Wang, K
Fu, Q
Zhang, CL
AF Tang, Changyu
Zhang, Qin
Wang, Ke
Fu, Qiang
Zhang, Chaoliang
TI Water transport behavior of chitosan porous membranes containing
multi-walled carbon nanotubes (MWNTs)
SO JOURNAL OF MEMBRANE SCIENCE
LA English
DT Article
DE Chitosan; Multi-walled carbon nanotubes; Polyethylene glycol; Porous
membrane; Water transport
ID MIXED MATRIX MEMBRANES; MECHANICAL-PROPERTIES; BLEND MEMBRANES; POLYMER
BLENDS; GAS SEPARATION; POLYSULFONE; FABRICATION; COMPOSITES;
MORPHOLOGY; FLUX
AB In this work., the effects of MWNTs content on water transport
behaviors and tensile properties of prepared chitosan porous membranes
were investigated. In the case of chitosan membrane using low molecular
weight PEG6000 as a porogen, a percolation-like behavior of water
transport rate was observed for the first time in composite membranes
with a critical MWNTs content (5 wt%). The water flux of composite
membrane with 10 wt% MWNTs (128.1 L/m(2) h) is 4.6 times that of neat
one (27.6 L/m(2) h). This could be understood as due to the formation
of MWNTs network located among the pore network of chitosan membrane at
high MWNTs content, where the hollow nanochannel of MWNTs and their
interspaces could provide a new transport channel for water. In
contrary, when high molecular weight PEG10000 is used as the porogen, a
decreased water flux of the prepared composite membrane is found with
increase of MWNTs content. In this case, a strong compatibilizing
effect of MWNTs on chitosan/PEG10000 blends is observed, resulting in a
decreased pore size and poor water flux of the membranes. Furthermore,
a greatly improved tensile strength of chitosan porous membranes has
been achieved by adding MWNTs, no matter which molecular weight PEG is
used as porogen. Our work provides a novel way to improve water flux
and/or control the pore size of polymer porous membranes by using
MWNTs. (C) 2009 Elsevier B.V. All rights reserved.
C1 [Tang, Changyu; Zhang, Qin; Wang, Ke; Fu, Qiang] Sichuan Univ, Dept Polymer Sci & Mat, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China.
[Zhang, Chaoliang] State Key Lab Oral Dis, Chengdu 610065, Peoples R China.
RP Fu, Q, Sichuan Univ, Dept Polymer Sci & Mat, State Key Lab Polymer Mat
Engn, Chengdu 610065, Peoples R China.
EM qiangfu@scu.edu.cn
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NR 36
TC 0
PU ELSEVIER SCIENCE BV; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
SN 0376-7388
DI 10.1016/j.memsci.2009.03.048
PD JUL 15
VL 337
IS 1-2
BP 240
EP 247
SC Engineering, Chemical; Polymer Science
GA 458LS
UT ISI:000267025500027
ER

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