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| Title: Wetting and spreading |
| Authors: |
| Author Full Names: Bonn, Daniel; Eggers, Jens; Indekeu, Joseph; Meunier, Jacques; Rolley, Etienne |
| Source: REVIEWS OF MODERN PHYSICS 81 (2): 739-805 APR-JUN 2009 |
| Language: English |
| Document Type: Review |
| KeyWords Plus: MOVING CONTACT-LINE; LONG-RANGE FORCES; COLLOID-POLYMER MIXTURES; LIQUID-VAPOR INTERFACES; CRITICAL CASIMIR FORCES; HARD-SPHERE MIXTURES; THIN FLUID FILMS; CHEMICALLY STRUCTURED SURFACES; MONTE-CARLO SIMULATIONS; DRIVEN COATING FILMS |
| Abstract: Wetting phenomena are ubiquitous in nature and technology. A solid substrate exposed to the environment is almost invariably covered by a layer of fluid material. In this review, the surface forces that lead to wetting are considered, and the equilibrium surface coverage of a substrate in contact with a drop of liquid. Depending on the nature of the surface forces involved, different scenarios for wetting phase transitions are possible; recent progress allows us to relate the critical exponents directly to the nature of the surface forces which lead to the different wetting scenarios. Thermal fluctuation effects, which can be greatly enhanced for wetting of geometrically or chemically structured substrates, and are much stronger in colloidal suspensions, modify the adsorption singularities. Macroscopic descriptions and microscopic theories have been developed to understand and predict wetting behavior relevant to microfluidics and nanofluidics applications. Then the dynamics! of wetting is examined. A drop, placed on a substrate which it wets, spreads out to form a film. Conversely, a nonwetted substrate previously covered by a film dewets upon an appropriate change of system parameters. The hydrodynamics of both wetting and dewetting is influenced by the presence of the three-phase contact line separating "wet" regions from those that are either dry or covered by a microscopic film only. Recent theoretical, experimental, and numerical progress in the description of moving contact line dynamics are reviewed, and its relation to the thermodynamics of wetting is explored. In addition, recent progress on rough surfaces is surveyed. The anchoring of contact lines and contact angle hysteresis are explored resulting from surface inhomogeneities. Further, new ways to mold wetting characteristics according to technological constraints are discussed, for example, the use of patterned surfaces, surfactants, or complex fluids. |
| Reprint Address: Bonn, D, Ecole Normale Super, Lab Phys Stat, 24 Rue Lhomond, F-75005 Paris, France. |
| Research Institution addresses: [Bonn, Daniel; Meunier, Jacques; Rolley, Etienne] Ecole Normale Super, Lab Phys Stat, F-75005 Paris, France; [Bonn, Daniel] Univ Amsterdam, Waals Zeeman Inst, NL-1018 XE Amsterdam, Netherlands; [Eggers, Jens] Univ Bristol, Sch Math, Bristol BS8 1TW, Avon, England; [Indekeu, Joseph] Katholieke Univ Leuven, Inst Theoret Fys, B-3001 Louvain, Belgium |
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| Cited Reference Count: 588 |
| Times Cited: 0 |
| Publisher: AMER PHYSICAL SOC; ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA |
| Subject Category: Physics, Multidisciplinary |
| ISSN: 0034-6861 |
| DOI: 10.1103/RevModPhys.81.739 |
| IDS Number: 460OR |
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