Thursday, July 9, 2009

ISI Web of Knowledge Alert - Holt JK

ISI Web of Knowledge Citation Alert

Cited Article: Holt JK. Fast mass transport through sub-2-nanometer carbon nanotubes
Alert Expires: 18 OCT 2009
Number of Citing Articles: 2 new records this week (2 in this e-mail)
Organization ID: 3b97d1bbc1878baed0ab183d8b03130b
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AU Peng, XS
Jin, J
Nakamura, Y
Ohno, T
Ichinose, I
AF Peng, Xinsheng
Jin, Jian
Nakamura, Yoshimichi
Ohno, Takahisa
Ichinose, Izumi
TI Ultrafast permeation of water through protein-based membranes
SO NATURE NANOTECHNOLOGY
LA English
DT Article
ID COPPER HYDROXIDE NANOSTRANDS; CARBON NANOTUBE MEMBRANES; FAST
MASS-TRANSPORT; ULTRAFILTRATION MEMBRANES; NANOFILTRATION MEMBRANES;
SEPARATION; MODEL
AB Pressure-driven filtration by porous membranes is widely used in the
production of drinking water from ground and surface water(1-3).
Permeation theory predicts that filtration rate is proportional to the
pressure difference across the filtration membrane and inversely
proportional to the thickness of the membrane(4). However, these
membranes need to be able to withstand high water fluxes and pressures,
which means that the active separation layers in commercial filtration
systems typically have a thickness of a few tens to several hundreds of
nanometres(5). Filtration performance might be improved by the use of
ultrathin porous silicon membranes(6) or carbon nanotubes immobilized
in silicon nitride(7) or polymer films(8,9), but these structures are
difficult to fabricate. Here, we report a new type of filtration
membrane made of crosslinked proteins that are mechanically robust and
contain channels with diameters of less than 2.2 nm. We find that a
60-nm-thick membrane can concentrate aqueous dyes from fluxes up to
9,000 l h(-1) m(-2) bar(-1), which is similar to 1,000 times higher
than the fluxes that can be withstood by commercial filtration
membranes with similar rejection properties(1,10,11). Based on these
results and molecular dynamics simulations, we propose that
protein-surrounded channels with effective lengths of less than 5.8 nm
can separate dye molecules while allowing the ultrafast permeation of
water at applied pressures of less than 1 bar.
C1 [Peng, Xinsheng; Jin, Jian; Ichinose, Izumi] Natl Inst Mat Sci, Organ Nanomat Ctr, Tsukuba, Ibaraki 3050044, Japan.
[Nakamura, Yoshimichi; Ohno, Takahisa] Natl Inst Mat Sci, Computat Mat Sci Ctr, Tsukuba, Ibaraki 3050047, Japan.
[Ohno, Takahisa; Ichinose, Izumi] JST, CREST, Chiyoda Ku, Tokyo 1020075, Japan.
RP Ichinose, I, Natl Inst Mat Sci, Organ Nanomat Ctr, 1-1 Namiki, Tsukuba,
Ibaraki 3050044, Japan.
EM ICHINOSE.lzumi@nims.go.jp
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NR 28
TC 1
PU NATURE PUBLISHING GROUP; MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1
9XW, ENGLAND
SN 1748-3387
DI 10.1038/NNANO.2009.90
PD JUN
VL 4
IS 6
BP 353
EP 357
SC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary
GA 459TA
UT ISI:000267131500011
ER

PT J
*Record 2 of 2.
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AU Ji, QM
Acharya, S
Hill, JP
Vinu, A
Yoon, SB
Yu, JS
Sakamoto, K
Ariga, K
AF Ji, Qingmin
Acharya, Somobrata
Hill, Jonathan P.
Vinu, Ajayan
Yoon, Suk Bon
Yu, Jong-Sung
Sakamoto, Kazutami
Ariga, Katsuhiko
TI Hierarchic Nanostructure for Auto-Modulation of Material Release:
Mesoporous Nanocompartment Films
SO ADVANCED FUNCTIONAL MATERIALS
LA English
DT Article
ID CONTROLLED DRUG-RELEASE; POLYELECTROLYTE MULTILAYER FILMS; RESPONSIVE
CONTROLLED-RELEASE; POROUS-GLASS PLATE; SUPRAMOLECULAR NANOVALVE;
CORE/MESOPOROUS SHELL; SILICA NANOPARTICLES; PERMEATION CONTROL;
TRIGGERED RELEASE; GUEST MOLECULES
AB The preparation of mesoporous nanocompartment films composed of both
hollow silica capsules and silica particles by using layer-by-layer
(LbL) adsorption is described. The resultant nanocompartment films
exhibit stepwise release, of encapsulated water molecules without
application of external stimuli. The hollow hierarchic pore structure
of the silica capsules, including their internal void and mesoporous
walls, is a key factor for the regulation and stepwise release of
water, and is probably caused by the non- equilibrated concurrent
evaporation of material from the mesopore and capillary penetration
into the mesopores. The number of release steps and rate of release can
be tuned by variation of several parameters including water content,
ambient temperature, layer multiplicity, and co-adduct particle size.
Application of the mesoporous nanocompartment films for the release of
substances, including therapeutic agents and fragrances, indicates that
the stepwise material release can be applied for a wide range of liquid
substances. The films should lead to a novel-material release system
useful even for biomedical applications capable of controlled and
sustained delivery of drug molecules.
C1 [Ji, Qingmin; Acharya, Somobrata; Hill, Jonathan P.; Vinu, Ajayan; Ariga, Katsuhiko] Natl Inst Mat Sci, World Premier Int Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan.
[Yoon, Suk Bon; Yu, Jong-Sung] Korea Univ, Dept Adv Mat Chem, Jochiwon 339700, Chungnam, South Korea.
[Sakamoto, Kazutami] Tokyo Univ Sci, Chiba 2788510, Japan.
RP Ji, QM, Natl Inst Mat Sci, World Premier Int Res Ctr Mat
Nanoarchitecton, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan.
EM jsyu212@korea.ac.kr
ARIGA.Katsuhiko@nims.go.jp
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NR 89
TC 0
PU WILEY-V C H VERLAG GMBH; PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY
SN 1616-301X
DI 10.1002/adfm.200801762
PD JUN 9
VL 19
IS 11
BP 1792
EP 1799
SC Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience &
Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied;
Physics, Condensed Matter
GA 461XA
UT ISI:000267305500015
ER

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